420042

1-Methyl-2-propenylmagnesium chloride solution

0.5 M in THF

• 化学式: H₂C=CHCH(CH₃)MgCl
• CAS番号: 21969-32-4
• 分子量: 114.86
• MDL番号: MFCD00216570
• UNSPSCコード: 12352103
• PubChem Substance ID: 24866306
• NACRES: NA.22

特性

• 品質水準: 100
• 反応適合性: reaction type: Grignard Reaction
• 濃度: 0.5 M in THF
• bp: 67 °C
• 密度: 0.917 g/mL at 25 °C
• SMILES記法: CC([Mg]Cl)C=C
• InChI: 1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1
• InChI Key: RTJGBPYEBKZQGE-UHFFFAOYSA-M

詳細

アプリケーション

1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.

安全性情報

• ピクトグラム: GHS02,GHS05,GHS07,GHS08
• シグナルワード: Danger
• 危険有害性情報: H225 - H261 - H302 - H314 - H335 - H351
• 注意書き: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH014 - EUH019
• 保管分類コード: 4.3 - Hazardous materials, which set free flammable gases upon contact with water
• WGK: WGK 3
• 引火点(°F): -4.0 °F - closed cup
• 引火点(℃): -20 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter