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M80903

Sigma-Aldrich

α-Methylstyrene

99%, contains 15 ppm p-tert-butylcatechol as inhibitor

Sinonimo/i:

2-Phenylpropene, Isopropenylbenzene

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About This Item

Formula condensata:
C6H5C(CH3)=CH2
Numero CAS:
Peso molecolare:
118.18
Beilstein:
969405
Numero CE:
Numero MDL:
Codice UNSPSC:
12162002
ID PubChem:
NACRES:
NA.23

Densità del vapore

4.1 (vs air)

Livello qualitativo

Tensione di vapore

2.1 mmHg ( 20 °C)

Saggio

99%

Stato

liquid

Temp. autoaccensione

1065 °F

contiene

15 ppm p-tert-butylcatechol as inhibitor

Limite di esplosione

6.1 %

Indice di rifrazione

n20/D 1.538 (lit.)

P. ebollizione

165-169 °C (lit.)

Punto di fusione

−24 °C (lit.)

Densità

0.909 g/mL at 25 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

CC(=C)c1ccccc1

InChI

1S/C9H10/c1-8(2)9-6-4-3-5-7-9/h3-7H,1H2,2H3
XYLMUPLGERFSHI-UHFFFAOYSA-N

Descrizione generale

-Methylstyrene is an aromatic alkyl-substituted styrene monomer with a relatively high boiling point. It is widely used as a monomer to synthesize thermoplastic composite resins applied in adhesives, and coatings that require high-temperature stability. It can also participate as a precursor in regioselective and diastereoselective synthesis of natural products, pharmaceuticals, and other structurally diverse compounds.

Applicazioni

α-Methylstyrene can be used:

  • As a monomer to prepare “Phene” monomer for photopolymerizable dental resin composites to reduce their polymerization shrinkage. α-Methylstyrene has a low double bond concentration suitable for the preparation of low volumetric shrinkage and shrinkage stress resilient resin composites.
  • As a monomer to prepare poly(α-methylstyrene) polymer which can be used as an additive to fabricate organic thin film transistors. This polymer promotes the growth of uniformly aligned semiconductor crystals with significantly improved orientation.
  • As a precursor to synthesize 3,4-dihydropyrans with therapeutic potential.

Avvertenze

Danger

Classi di pericolo

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - Skin Sens. 1B - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

114.8 °F - closed cup

Punto d’infiammabilità (°C)

46 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Mikrobiologiia, 54(1), 136-140 (1985-01-01)
The work was aimed at studying alpha-methylstyrene oxidation by three active Pseudomonas cultures. P. acidovorans 9 oxidized alpha-methylstyrene only to acetophenone whereas two P. aeruginosa cultures assimilated the compound entirely. Analysis of the intermediate products and enzymes catalyzing the aromatic
National Toxicology Program technical report series, (543)(543), 1-210 (2008-08-08)
alpha-Methylstyrene is used in the production of acrylonitrile-butadiene-styrene resins and copolymers, which improve the impact and heat-resistant properties of polymers, specialty grades of plastics, rubber, and protective coatings. alpha-Methylstyrene also moderates polymerization rates and improves product clarity in coatings and

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