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A24109

Sigma-Aldrich

Acryloyl chloride

≥97%, contains ~400 ppm phenothiazine as stabilizer

Sinonimo/i:

Acrylic acid chloride, prop-2-enoyl chloride, 2-Propenoyl chloride

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About This Item

Formula condensata:
CH2=CHCOCl
Numero CAS:
814-68-6
Peso molecolare:
90.51
Beilstein:
635744
Numero CE:
212-399-0
Numero MDL:
MFCD00000731
Codice UNSPSC:
12162002
ID PubChem:
24890654
NACRES:
NA.23

Densità del vapore

>1 (vs air)

Livello qualitativo

200

Tensione di vapore

1.93 psi ( 20 °C)

Saggio

≥97%

Stato

liquid

contiene

~400 ppm phenothiazine as stabilizer

Indice di rifrazione

n20/D 1.435 (lit.)

P. ebollizione

72-76 °C (lit.)

Densità

1.114 g/mL at 25 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

ClC(=O)C=C

InChI

1S/C3H3ClO/c1-2-3(4)5/h2H,1H2
HFBMWMNUJJDEQZ-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Acryloyl chloride, an organic chemical compound, serves primarily as a reactive monomer for synthesizing polymers and copolymers applicable in diverse fields like adhesives, coatings, hydrogel coatings, sustained drug release, hydrogel film, organic electronic devices and plastics. Phenothiazine is commonly used as a stabilizer for acryloyl chloride during polymerization. It is added in small quantities (400ppm), to prevent the formation of unwanted by-products and to extend the shelf life of the reactive monomer. It also acts as a scavenger for free radicals that may form during the polymerization process.

Applicazioni

Acryloyl chloride can be used as:
  • A monomer to synthesize crosslinked zwitterionic hydrogel coatings for sensing and detection in complex media.
  • A reactant to synthesize crosslinked hydrogel film by reacting with a hydrophilic monomer called N,N-(dimethylacrylamide) (DMAA). The prepared hydrogel film is further used in sustained drug delivery.
  • A monomer in the preparation of acrylate-based polymers with excellent n-type semiconducting properties, which are important for the development of organic electronic devices.
  • The cyclam monomer. The polymer of this modified cyclam monomer can be used in specific transition metal binding.

Avvertenze

Danger

Indicazioni di pericolo

H225,H290,H302,H314,H330

Classi di pericolo

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A

Rischi supp

EUH014

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

30.2 °F

Punto d’infiammabilità (°C)

-1 °C

Elenchi normativi

Forniamo informazioni su eventuali restrizioni prevalentemente per i prodotti chimici. Per altre tipologie di prodotto siamo in grado di fornire soltanto informazioni limitate. Nessuna segnalazione significa che nessuno dei componenti è citato in un elenco. È dovere dell’utilizzatore assicurarsi che il prodotto venga impiegato in maniera sicura e a norme di legge.

EU REACH Annex XVII (Restriction List)

CAS No.

Scegli una delle versioni più recenti:

Certificati d'analisi (COA)

Lot/Batch Number
STBK7990
STBK3462
STBK6489
STBK5212
SHBP2133

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Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 58(2), 209-217 (2003-02-08)
An automated procedure for the radiosynthesis of the labeling synthon [11C]acryloyl chloride was developed and applied for labeling several N-acryl amides with carbon-11. [11C]-6-acrylamido-4-(3,4-dichloro-6-fluoroanilino)quinazoline (ML03), a novel PET biomarker targeting the epidermal growth factor receptor tyrosine kinase (EGFr-TK) in cancer
V Fulcrand et al.
International journal of peptide and protein research, 38(3), 273-277 (1991-09-01)
Copolymers of acrylated derivatives of alpha-chymotrypsin and polyethylene glycol (PEG) have been prepared and used as biocatalysts for the synthesis of model peptides in organic solvent containing a low quantity of water. Other peptide couplings have been tried to point
J C Tiller et al.
Proceedings of the National Academy of Sciences of the United States of America, 98(11), 5981-5985 (2001-05-17)
Poly(4-vinyl-N-alkylpyridinium bromide) was covalently attached to glass slides to create a surface that kills airborne bacteria on contact. The antibacterial properties were assessed by spraying aqueous suspensions of bacterial cells on the surface, followed by air drying and counting the
Gang-Long Cui et al.
The journal of physical chemistry. A, 110(42), 11839-11846 (2006-10-20)
The potential energy surfaces of isomerization and dissociation reactions for CH2CHCOCl in the S0, T1, T2, and S1 states have been mapped with DFT, CASSCF, MP2, and MR-CI calculations. Rate constants for adiabatic and nonadiabatic processes have been calculated with
R Bahulekar et al.
Biomaterials, 20(4), 357-362 (1999-02-27)
Poly(N-alkyl mono and disubstituted) acrylamide derivatives were synthesized from poly(acryloyl chloride) by monomer analogous reaction. The polymers were characterized by FTIR-ATR and GPC. The contact angle measurements were performed to evaluate hydrophobic/hydrophilic characters of these polymers. The N-alkyl substituents changed
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Global Trade Item Number

SKUGTIN
A24109-100ML4061837403491
A24109-500ML4061837403538
A24109-100G4061833350201
A24109-1KG4061833350218
A24109-1L4061837403507
A24109-25KG
A24109-500G4061837403521
A24109-5G4061833350225
A24109-5ML4061837403545

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