903973

Thianthrene S-oxide

≥95%

• Sinonimo/i: Non-fluorinated sulfoxide-based thianthrene reagent, Thianthrene 5-oxide
• Formula empirica (notazione di Hill): C₁₂H₈OS₂
• Numero CAS: 2362-50-7
• Peso molecolare: 232.32
• Numero MDL: MFCD01464038
• Codice UNSPSC: 12352119
• NACRES: NA.22

Proprietà

• Saggio: ≥95%
• Forma fisica: powder
• Gruppo funzionale: sulfoxide; thioether
• Temperatura di conservazione: 2-8°C
• InChI: 1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H; NYVGTLXTOJKHJN-UHFFFAOYSA-N

Descrizione

Applicazioni

Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent.

Altre note

Site-selective and versatile aromatic C-H functionalization by thianthrenation

Video: Site-selective C-H functionalization by thianthrenation

In the Pipeline: New Chemistry, Making New Things

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Note legali

Patent Application EP18204755.5
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable