798711

(R)-Xyl-SDP(O)

• Sinonimo/i: (R)-Xyl-SDP Oxide, [(1R)-7′-[Bis(3,5-dimethylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobi[1H-inden]-7-yl]bis(3,5-dimethylphenyl)phosphine oxide
• Formula empirica (notazione di Hill): C₄₉H₅₀OP₂
• Numero CAS: 1462321-89-6
• Peso molecolare: 716.87
• Numero MDL: MFCD28987326
• Codice UNSPSC: 12352000
• ID PubChem: 329768666
• NACRES: NA.22

Proprietà

• Saggio: ≥95%
• Livello qualitativo: 100
• Stato: solid
• Gruppo funzionale: phosphine oxide; phosphine
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: CC1=CC(C)=CC(P(C2=CC(C)=CC(C)=C2)(C3=CC=CC4=C3[C@]5(CCC6=C5C(P(C7=CC(C)=CC(C)=C7)C8=CC(C)=CC(C)=C8)=CC=C6)CC4)=O)=C1
• InChI: 1S/C49H50OP2/c1-31-19-32(2)24-41(23-31)51(42-25-33(3)20-34(4)26-42)45-13-9-11-39-15-17-49(47(39)45)18-16-40-12-10-14-46(48(40)49)52(50,43-27-35(5)21-36(6)28-43)44-29-37(7)22-38(8)30-44/h9-14,19-30H,15-18H2,1-8H3/t49-/m1/s1; ZAQVAUFRFBAVHF-ANFMRNGASA-N

Descrizione

Applicazioni

Chiral ligand introduced in collaboration with Prof. Steve Zhou and coworkers, has shown utility in asymmetric Heck reactions for both intra and intermolecular C-C bond formation with various triflates and halides.

Altre note

Palladium-Catalyzed Asymmetric Intermolecular Cyclization

Asymmetric Intermolecular Heck Reaction of Aryl Halides

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable