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700703

Sigma-Aldrich

N-tert-Butyl-N-(2-methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylamine

Sinonimo/i:

2,2,5-Trimethyl-3-(1-phenylethoxy)-4-phenyl-3-azahexane, Alkoxyamine NMP initiator

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About This Item

Formula empirica (notazione di Hill):
C22H31NO
Numero CAS:
227000-59-1
Peso molecolare:
325.49
Numero MDL:
MFCD12546017
Codice UNSPSC:
12162002
ID PubChem:
329762224
NACRES:
NA.23

Forma fisica

liquid

Livello qualitativo

100

Indice di rifrazione

n20/D 1.536

Densità

0.968 g/mL at 25 °C

Temperatura di conservazione

−20°C

Stringa SMILE

CC(C)C(N(OC(C)c1ccccc1)C(C)(C)C)c2ccccc2

InChI

1S/C22H31NO/c1-17(2)21(20-15-11-8-12-16-20)23(22(4,5)6)24-18(3)19-13-9-7-10-14-19/h7-18,21H,1-6H3
FPFRTDOMIFBPBZ-UHFFFAOYSA-N

Descrizione generale

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Applicazioni

Block Copolymer Synthesis Using a Commercially Available NMP Inititator

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
MKCN6739
MKCC2057
MKBN3244V
MKBH3384V
MKBF5807V

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I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

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Benoit, D., Chaplinski, V., Braslau, R., Hawker, C.J.
Journal of the American Chemical Society, 121, 3904-3904 (1999)

Articoli

Block Copolymer Synthesis Using a Nitroxide-mediated Radical Polymerization (NMP) Approach

Block Copolymer Synthesis Using a Nitroxide-mediated Radical Polymerization (NMP) Approach

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Tools for Performing ATRP

Tools for Performing ATRP

Vedi tutto

Protocolli

Concepts and Tools for RAFT Polymerization

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Typical Procedures for Polymerizing via ATRP

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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