682373

[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium(II)

Umicore

• Sinonimo/i: Hoveyda-Grubbs Catalyst^® M72 SI(o-Tol) (C571), Dichloro[1,3-bis(2-methylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II), Stewart-Grubbs catalyst
• Formula empirica (notazione di Hill): C₂₇H₃₀Cl₂N₂ORu
• Numero CAS: 927429-61-6
• Peso molecolare: 570.52
• Numero MDL: MFCD09265166
• Codice UNSPSC: 12161600
• ID PubChem: 24885712
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Impiego in reazioni chimiche: core: ruthenium; reagent type: catalyst; reaction type: Ring-Opening Polymerization
• Punto di fusione: 199-208 °C
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3ccccc3C)c4ccccc4C
• InChI: 1S/C17H18N2.C10H12O.2ClH.Ru/c1-14-7-3-5-9-16(14)18-11-12-19(13-18)17-10-6-4-8-15(17)2;1-8(2)11-10-7-5-4-6-9(10)3;;;/h3-10H,11-12H2,1-2H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2; ZDJCARGGZRTYFH-UHFFFAOYSA-L

Descrizione

Descrizione generale

Learn more about our metathesis catalysts

Applicazioni

Less sterically hindered analog of Hoveyda-Grubbs Catalyst^® 2^nd Generation. Excels at ring-closing metathesis reactions of sterically encumbered olefins. Also useful for the cross metathesis of olefins bearing large allylic substituents.

Altre note

Grubbs Catalyst^® Technology for Olefin Metathesis by Aldrich

Note legali

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable