532711
2-Fluorobenzenesulfonyl chloride
97%
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About This Item
Prodotti consigliati
Livello qualitativo
Saggio
97%
Indice di rifrazione
n20/D 1.537 (lit.)
P. eboll.
246-247 °C (lit.)
Punto di fusione
27-30 °C (lit.)
Densità
1.47 g/mL at 25 °C (lit.)
Stringa SMILE
Fc1ccccc1S(Cl)(=O)=O
InChI
1S/C6H4ClFO2S/c7-11(9,10)6-4-2-1-3-5(6)8/h1-4H
ZSZKAQCISWFDCQ-UHFFFAOYSA-N
Categorie correlate
Descrizione generale
2-Fluorobenzenesulfonyl chloride, also known as o-fluorobenzenesulfonyl chloride, is a flurinated arylsulfonyl chloride. It can be prepared from o-benzenedisulfonyl fluoride.
Applicazioni
2-Fluorobenzenesulfonyl chloride may be used in the preparation of the following furan derivatives:
It may also be used to prepare:
- 2-(2-fluorophenyl)benzofuran
- 2-butyl-5-(2-fluorophenyl)furan
- 2-(2-fluorophenyl)-3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran
It may also be used to prepare:
- 2-fluorobenzenesulfonamide
- methyl 2-{[(2-fluorophenyl)sulfonyl]amino}-5,6,7,8-tetrahydro-1-naphthalenecarboxylate
- potassium fluorobenzene-2-sulfonate
- 1-(2-bromobenzyl)-2-(2-fluorophenyl)pyrrole
Avvertenze
Danger
Indicazioni di pericolo
Classi di pericolo
Eye Dam. 1 - Skin Corr. 1B
Codice della classe di stoccaggio
8A - Combustible corrosive hazardous materials
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
230.0 °F - closed cup
Punto d’infiammabilità (°C)
110 °C - closed cup
Dispositivi di protezione individuale
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Water-Soluble Phosphines. 6.1 Tailor-Made Syntheses of Chiral Secondary and Tertiary Phosphines with Sulfonated Aromatic Substituents: Structural and Quantum Chemical Studies.
Inorganic Chemistry, 35(14), 4103-4113 (1996)
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ChemCatChem, 6(5), 1303-1309 (2014)
Potassium fluoride catalyzed fluorodesulfonylations of aryl sulfonyl fluorides.
The Journal of Organic Chemistry, 53(18), 4398-4401 (1988)
Benzenesulfonyl Chlorides: Alternative Coupling Partners for Regiocontrolled Palladium-Catalyzed Direct Desulfitative 5-Arylation of Furans.
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