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522805

Sigma-Aldrich

4-(Dimethylamino)pyridine

≥99%

Sinonimo/i:

N,N-Dimethylpyridin-4-amine, DMAP

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About This Item

Formula empirica (notazione di Hill):
C7H10N2
Numero CAS:
1122-58-3
Peso molecolare:
122.17
Beilstein:
110354
Numero CE:
214-353-5
Numero MDL:
MFCD00006418
Codice UNSPSC:
12352000
ID PubChem:
24874122

Saggio

≥99%

Punto di fusione

108-110 °C (lit.)

Stringa SMILE

CN(C)c1ccncc1

InChI

1S/C7H10N2/c1-9(2)7-3-5-8-6-4-7/h3-6H,1-2H3
VHYFNPMBLIVWCW-UHFFFAOYSA-N

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Applicazioni

A highly efficient catalyst for acylation reactions

Altre note

This product has been replaced by 107700-ALDRICH | 4-(Dimethylamino)pyridine ReagentPlus®, ≥99%

Note legali

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Avvertenze

Danger

Classi di pericolo

Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 1

Organi bersaglio

Nervous system

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

255.2 °F

Punto d’infiammabilità (°C)

124 °C

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
BCBH0386V
MKBJ1553V
MKBJ4137V
BCBG7096V
BCBF2007V

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Sigma-Aldrich

03450

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Di-tert-butyl dicarbonate ReagentPlus®, ≥99%

Sigma-Aldrich

361941

Di-tert-butyl dicarbonate

Anitha Devadoss et al.
Analytical chemistry, 83(6), 2383-2387 (2011-03-03)
Metallopolymer-gold nanocomposites have been synthesized in which the metal complex-Au nanoparticle (NP) mole ratio is systematically varied by mixing solutions of 4-(dimethylamino) pyridine protected gold nanoparticles and a [Ru(bpy)(2)PVP(10)](2+) metallopolymer; bpy is 2,2'-bipyridyl and PVP is poly-(4-vinylpyridine). The impact of
Matthieu Sainlos et al.
Journal of the American Chemical Society, 131(19), 6680-6682 (2009-04-25)
A systematic and general approach for identifying efficient probes for class I PDZ domains based on environment-sensitive chromophores is presented. A series of peptides derived from the C-terminal sequence of Stargazin was first used with PDZ domains of PSD-95 and
C Jesintha John et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 81(1), 151-161 (2011-07-09)
Vibrational spectra of the organic nonlinear optical crystallized dimethyl amino pyridinium 4-nitrophenolate 4-nitrophenol have been recorded and analyzed. The spectral interpretation has been done based on the density functional theory using the standard B3LYP/LANL2DZ basis set. Total energy distribution is
Falk Muench et al.
Langmuir : the ACS journal of surfaces and colloids, 27(1), 430-435 (2010-12-08)
Gold nanotubes of small particle sizes down to 5 nm and high aspect ratios were synthesized in ion track etched polycarbonate following a rational reaction design. 4-(Dimethylamino)pyridine (DMAP) was employed to adjust the electroless deposition by interfering with the autocatalytically
Marie-Laure Teyssot et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(26), 6322-6326 (2009-05-23)
A simple addition with a large impact: Addition of aromatic amines such as phenanthroline and 4-DMAP (4-dimethylaminopyridine) increases copper(I)-catalyzed azide alkyne cycloaddition (CuAAC) catalytic activity of [CuCl(SIMes)] at a large range of temperatures in such a way that efficient catalysis
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