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379840

Sigma-Aldrich

Platinum(IV) chloride

≥99.99% trace metals basis

Sinonimo/i:

Platinum tetrachloride

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About This Item

Formula condensata:
PtCl4
Numero CAS:
13454-96-1
Peso molecolare:
336.89
Numero CE:
236-645-1
Numero MDL:
MFCD00011182
Codice UNSPSC:
12352302
ID PubChem:
24863693
NACRES:
NA.23

Livello qualitativo

100

Saggio

≥99.99% trace metals basis

Forma fisica

powder and chunks

Impiego in reazioni chimiche

reagent type: catalyst
core: platinum

Impurezze

≤100.0 ppm Trace Metal Analysis

Punto di fusione

370 °C (dec.) (lit.)

Densità

4.303 g/mL at 25 °C (lit.)

Stringa SMILE

Cl[Pt](Cl)(Cl)Cl

InChI

1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4
FBEIPJNQGITEBL-UHFFFAOYSA-J

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Descrizione generale

Platinum (IV)chloride is a highly oxidizing crystalline compound that can easily undergo reduction-oxidation reactions. It is widely used to synthesize Pt-based nanomaterials and catalysts.

Applicazioni

Platinum (IV) chloride can be used:
  • As a precursor to synthesize Pt nanoparticles for photocatalytic hydrogen generation.
  • As a starting material to prepare Pt/Al2O3 and Pt/ZrO2-SiO2 catalysts.
  • To fabricate an electrocatalyst for proton exchange fuel cells.
  • As a catalyst for the cyclization of arene−alkynesubstrates via intramolecular electrophilic hydroarylation.

Avvertenze

Danger

Indicazioni di pericolo

H301,H314,H317,H334

Classi di pericolo

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
MKCQ9423
MKCM8210
MKCM0871
MKCL4472
MKCK5049

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N Kanematsu et al.
Gifu Shika Gakkai zasshi = The Journal of Gifu Dental Society, 17(2), 575-581 (1990-12-01)
The induction of mutation by cadmium chloride (CdCl2), platinum tetrachloride (PtCl4), and rhodium trichloride (RhCl3.3H2O) was measured utilizing the hypoxanthine-guanine phosphoribosyl transferase (HGPRT) locus in V-79 cells. Cadmium chloride at a concentration of 0.05 microM induced ford mutation in V-79
Eric Ennifar et al.
Nucleic acids research, 31(10), 2671-2682 (2003-05-09)
Metal ions, and magnesium in particular, are known to be involved in RNA folding by stabilizing secondary and tertiary structures, and, as cofactors, in RNA enzymatic activity. We have conducted a systematic crystallographic analysis of cation binding to the duplex
B A Teicher et al.
Anticancer research, 13(5A), 1549-1556 (1993-09-01)
Since several anticancer drugs are known to become more cytotoxic to cells in an acidic milieu, we have attempted to utilize the carbonic anhydrase inhibitor, Acetazolamide, to acidify the blood and tumor of C3H mice bearing the FSaIIC fibrosarcoma in
A M Reichlmayr-Lais et al.
Journal of trace elements and electrolytes in health and disease, 6(3), 183-187 (1992-09-01)
In experiments with rats dose-response relationships of alimentary PtCl2 and PtCl4 were investigated. 2 x 81 animals weighing 35 g were randomly distributed among 9 treatment groups which were fed ad libitum with a synthetic diet containing various amounts of
Ivana Bednarova et al.
Neuro endocrinology letters, 33 Suppl 3, 107-112 (2013-01-29)
An enhanced worldwide application of platinum group elements (PGE), in particular platinum, has been observed during recent decades. An increased concentration of PGE was determined in collected samples of great amount of aqueous ecosystems.The aim was to compare phytotoxic effect
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