358711

Tetraethylammonium cyanide

94%

• Sinonimo/i: N,N,N-triethyl-ethanaminium cyanide
• Formula condensata: (C₂H₅)₄N(CN)
• Numero CAS: 13435-20-6
• Peso molecolare: 156.27
• Beilstein: 3570222
• Numero CE: 236-566-2
• Numero MDL: MFCD00066552
• Codice UNSPSC: 12352116
• ID PubChem: 24861985
• NACRES: NA.22

Proprietà

• Livello qualitativo: 200
• Saggio: 94%
• Stato: powder
• Punto di fusione: 250 °C (dec.) (lit.)
• Stringa SMILE: [C-]#N.CC[N+](CC)(CC)CC
• InChI: 1S/C8H20N.CN/c1-5-9(6-2,7-3)8-4;1-2/h5-8H2,1-4H3;/q+1;-1; PCZOZSATUTWXIC-UHFFFAOYSA-N

Descrizione

Applicazioni

Tetraethylammonium cyanide can be used:

• As a cyanide source for 1,4-addition of cyano group to enones (chalcones) catalyzed by scandium(III) triflate to yield β-cyanoketones.
• Along with diethylazodicarboxylate (DEAD) in the regioselective C- or N- ethoxy-carbonylation of heterocyclic systems like indoles and indazoles.
• In the synthesis of C-C-bridged bis-isoflavones from 2-bromomethyl-7,4′-dimethoxyisoflavone.

Tetraethylammonium cyanide is a versatile reagent commonly used in cyanation reactions as cyanide source. It is also used in the preparation of various cyanometalate complexes.

Informazioni sulla sicurezza

• Pittogrammi: GHS06,GHS09
• Avvertenze: Danger
• Indicazioni di pericolo: H300 + H310 + H330,H410
• Consigli di prudenza: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310
• Classi di pericolo: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• Rischi supp: EUH032
• Codice della classe di stoccaggio: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges