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235202

Sigma-Aldrich

4-Bromomethyl-7-methoxycoumarin

97%

Sinonimo/i:

BMC, Br-Mmc

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About This Item

Formula empirica (notazione di Hill):
C11H9BrO3
Numero CAS:
35231-44-8
Peso molecolare:
269.09
Beilstein:
187211
Numero CE:
252-448-3
Numero MDL:
MFCD00006869
Codice UNSPSC:
12352100
ID PubChem:
24854087
NACRES:
NA.22

Saggio

97%

Stato

solid

Punto di fusione

213-215 °C (lit.)

Solubilità

chloroform: soluble 20 mg/mL, clear, colorless to faintly yellow

Fluorescenza

λex 322 nm; λem 395 nm (after derivatization)

Gruppo funzionale

bromo
ester

Stringa SMILE

COc1ccc2C(CBr)=CC(=O)Oc2c1

InChI

1S/C11H9BrO3/c1-14-8-2-3-9-7(6-12)4-11(13)15-10(9)5-8/h2-5H,6H2,1H3
CTENSLORRMFPDH-UHFFFAOYSA-N

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Applicazioni

4-Bromomethyl-7-methoxycoumarin has been used:
  • as derivatization reagent in determination of 5-fluorouracil (5-FU) in human plasma by HPLC-tandem mass spectrometry
  • as derivatization reagent in fluorescence detection of sodium monofluoroacetate (MFA-Na) in biological samples by HPLC
  • in the synthesis of new caged derivatives of hydrolysis-resistant 8-bromoadenosine cyclic 3′,5′-monophosphate (8-Br-cAMP) and 8-bromoguanosine cyclic 3′,5′-monophosphate (8-Br-cGMP)
  • in TLC and HPLC separation and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B2
Fluorescent label for fatty acids.

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H302,H315,H319,H335

Classi di pericolo

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

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Certificati d'analisi (COA)

Lot/Batch Number
BCBD4906V
BCBD4907V
BCBD4941V
BCBD3081V
BCBD2163V

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