175552
Trichlorosilane
99%
Sinonimo/i:
Hydrotrichlorosilane, Silicochloroform, Silicon chloride hydride, Trichloromonosilane
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About This Item
Formula condensata:
SiHCl3
Numero CAS:
Peso molecolare:
135.45
Numero CE:
Numero MDL:
Codice UNSPSC:
12352101
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Densità del vapore
1 (vs air)
Livello qualitativo
Tensione di vapore
9.75 psi ( 20 °C)
Saggio
99%
Forma fisica
liquid
Limite di esplosione
70 %
P. eboll.
32-34 °C (lit.)
Densità
1.342 g/mL at 25 °C (lit.)
Temperatura di conservazione
2-8°C
Stringa SMILE
Cl[SiH](Cl)Cl
InChI
1S/Cl3HSi/c1-4(2)3/h4H
ZDHXKXAHOVTTAH-UHFFFAOYSA-N
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Categorie correlate
Descrizione generale
Trichlorosilane is used as a reducing agent in certain chemical reactions or as a starting material for the synthesis of various organosilicon compounds. Trichlorosilane is generally used for the asymmetric hydrosilylation of olefins in the presence of palladium catalysts coordinated with chiral monodentate phosphorus ligands to generate chiral organosilanes.
Applicazioni
Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphosphinoyl-12-phenyl-9,10-dihydro-9,10-ethenoanthracene.
Other possible applications:
L-valine-derived catalyst to form secondary amines.
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.
Other possible applications:
- Asymmetric reduction of N-aryl ketimines in the presence of a novel
L-valine-derived catalyst to form secondary amines.
- Hydrosilylation of imidazolinones to form chiral imidazolidinones in the presence of a 2,2′-bispyrrolidine based Lewis base organocatalyst.
- Trichlorosilane activated with chiral N-formylproline
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.
- Trichlorosilane reacts with dimethylformamide to form hypervalent hydridosilicates, which can reduce aldehydes to alcohols, imines to amines, and also for the reductive amination of aldehydes.
Avvertenze
Danger
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1A - Water-react 1
Rischi supp
Codice della classe di stoccaggio
4.3 - Hazardous materials which set free flammable gases upon contact with water
Classe di pericolosità dell'acqua (WGK)
WGK 1
Punto d’infiammabilità (°F)
<-2.2 °F - Equilibrium method
Punto d’infiammabilità (°C)
< -19 °C - Equilibrium method
Dispositivi di protezione individuale
Faceshields, Gloves, Goggles
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