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103748

Sigma-Aldrich

2,3,4,5,6-Pentafluorobenzaldehyde

98%

Sinonimo/i:

Formylpentafluorobenzene, Pentafluorobenzaldehyde

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About This Item

Formula condensata:
C6F5CHO
Numero CAS:
653-37-2
Peso molecolare:
196.07
Beilstein:
1876550
Numero CE:
211-502-6
Numero MDL:
MFCD00003303
Codice UNSPSC:
12352100
ID PubChem:
24846620
NACRES:
NA.22

Livello qualitativo

200

Saggio

98%

Indice di rifrazione

n20/D 1.45 (lit.)

P. eboll.

164-166 °C (lit.)

Punto di fusione

24-28 °C (lit.)

Densità

1.588 g/mL at 25 °C (lit.)

Stringa SMILE

Fc1c(F)c(F)c(C=O)c(F)c1F

InChI

1S/C7HF5O/c8-3-2(1-13)4(9)6(11)7(12)5(3)10/h1H
QJXCFMJTJYCLFG-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

2,3,4,5,6-Pentafluorobenzaldehyde reacts with 5-(aryl)dipyrromethanes to form a variety of meso-aryl [26]hexaphyrins.

Applicazioni

2,3,4,5,6-Pentafluorobenzaldehyde was used in the synthesis of novel, high molecular weight fluorinated aromatic polymers by superacid-catalyzed polyhydroxylation reaction of fluorinated carbonyl-containing compounds. 2,3,4,5,6-Pentafluorobenzaldehyde was used as derivatization reagent in a study to develop a sensitive method for the determination of primary amines in sewage sludge by headspace solid-phase microextraction and gas chromatography-tandem mass spectrometry.

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H315 - H319 - H332 - H335

Classi di pericolo

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

170.6 °F - closed cup

Punto d’infiammabilità (°C)

77 °C - closed cup

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificati d'analisi (COA)

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Sigma-Aldrich

128376

4-Fluorobenzaldehyde

5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin ≥90.0% (HPLC)

Sigma-Aldrich

252921

5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin

Masaaki Suzuki et al.
Organic letters, 5(21), 3943-3946 (2003-10-11)
[reaction: see text] Acid-catalyzed reactions of 5-(2',3',4',5',6'-pentafluorophenyl)dipyrromethane with aryl aldehydes and of 5-(aryl)dipyrromethanes with 2,3,4,5,6-pentafluorobenzaldehyde allowed the preparation of a variety of meso-aryl [26]hexaphyrins.
Anna Llop et al.
Analytica chimica acta, 665(2), 231-236 (2010-04-27)
In this paper we describe an environmentally friendly and sensitive method for the determination of ten primary amines in sewage sludge. The method is based on pressurised hot water extraction (PHWE) followed by simultaneous derivatization with pentafluorobenzaldehyde (PFBAY) and headspace
Amit Kumar et al.
Dalton transactions (Cambridge, England : 2003), 48(30), 11345-11351 (2019-07-06)
Catalytic water splitting is a highly promising area of research for the development of a hydrogen-based society. Herein, the synthesis of the bifunctional A2B-type cobalt(iii) corrole Co(BAPC)Py2 having the electron-withdrawing meso-pentafluorophenyl and the basic meso-p-aminophenyl substituents is reported. Cyclic voltammetric
A Novel, One-Pot Synthesis of Novel 3F, 5F, and 8F Aromatic Polymers.
Diaz AM, et al.
Macromolecular Rapid Communications, 28(2), 183-187 (2007)
Cláudia M B Neves et al.
Journal of hazardous materials, 370, 13-23 (2018-12-07)
Porphyrins are known as effective photosensitizers and can be an interesting key in phototreatment of water contaminated with micropollutants such as pharmaceuticals. They already showed to be efficient photocatalysts for the degradation of dyes, chlorophenols and other pollutants. This work
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