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Merck

44939

Sigma-Aldrich

氯化亚铁 四水合物

puriss. p.a., ≥99.0% (RT)

别名:

氯化亚铁 四水合物

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About This Item

线性分子式:
FeCl2 · 4H2O
CAS号:
分子量:
198.81
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21

蒸汽壓力

10 mmHg ( 693 °C)

品質等級

等級

puriss. p.a.

化驗

≥99.0% (RT)

形狀

powder or crystals

雜質

≤0.001% total nitrogen (N)

pH值

2.5 (20 °C, 100 g/L)

負離子痕跡

sulfate (SO42-): ≤100 mg/kg

正離子痕跡

As: ≤5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤50 mg/kg
Cr: ≤10 mg/kg
Cu: ≤5 mg/kg
Fe3+: ≤2000 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤50 mg/kg
Na: ≤50 mg/kg
Ni: ≤50 mg/kg
Pb: ≤10 mg/kg
Zn: ≤20 mg/kg

SMILES 字串

O.O.O.O.Cl[Fe]Cl

InChI

1S/2ClH.Fe.4H2O/h2*1H;;4*1H2/q;;+2;;;;/p-2

InChI 密鑰

WSSMOXHYUFMBLS-UHFFFAOYSA-L

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應用

氯化铁(II)四水合物可以作为催化剂用于:
  • 腈和各种卤代烃合成 N-取代酰胺的无溶剂Ritter反应。
  • 炔间接水化反应合成酮。
  • 在锂和DTBB的参与下立体选择性地将 α, β-不饱和羰基化合物还原成相应的饱和醇。
它也可以用作制备铁-双膦配合物的前体,该配合物可以用于催化Kumada­-Tamao-­Corriu偶联。

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Dam. 1

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

does not flash

閃點(°C)

does not flash


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Maren Depke et al.
Cytometry. Part A : the journal of the International Society for Analytical Cytology, 85(2), 140-150 (2013-12-19)
Throughout the world, infections caused by bacteria such as Staphylococcus aureus are a major cause of morbidity and mortality. In order to gain some understanding of the complicated physiological link between host and pathogen, modern techniques such as confocal microscopy
The crystal structure of iron (II) chloride tetrahydrate.
Penfold BR and Grigor JA.
Acta Crystallographica, 12(11), 850854-850854 (1959)
Chenglong Yuan et al.
International journal of molecular sciences, 20(3) (2019-02-13)
The prion protein (PrPSc) has drawn widespread attention due to its pathological potential to cause prion diseases. Herein, we successfully synthesized Fe₃C@C by carbonizing Fe₃O₄-lignin clusters, which were prepared through a facile hydrogen bonding interaction between ≡Fe-OH and hydroxyl groups
Electron microscopy study of CVT grown Fe-sulphides.
Zavasnik J and Recnik A.
Journal of Crystal Growth, 367, 18-23 (2013)
Chong Qin et al.
Angewandte Chemie (International ed. in English), 51(28), 6971-6975 (2012-06-13)
Ironing it out: an efficient and convenient nitrogenation strategy involving C-C bond cleavage for the straightforward synthesis of versatile arylamines is presented. Various alkyl azides and alkylarenes, including the common industrial by-product cumene, react using this protocol. Moreover, this method

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