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Merck

12309

Supelco

p-苯醌

for spectrophotometric det. of amines, ≥99.5% (HPLC)

别名:

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About This Item

线性分子式:
C6H4(=O)2
CAS号:
分子量:
108.09
Beilstein:
773967
EC號碼:
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.21

蒸汽密度

3.73 (vs air)

品質等級

蒸汽壓力

0.1 mmHg ( 25 °C)

化驗

≥99.5% (HPLC)

形狀

powder or crystals

自燃溫度

815 °F

品質

for spectrophotometric det. of amines

技術

UV/Vis spectroscopy: suitable

升華殘留物

≤0.1%

顏色

, Faint Yellow to Very Dark Yellow to Very Dark Beige and Green-Yellow

mp

112-114 °C
113-115 °C (lit.)

SMILES 字串

O=C1C=CC(=O)C=C1

InChI

1S/C6H4O2/c7-5-1-2-6(8)4-3-5/h1-4H

InChI 密鑰

AZQWKYJCGOJGHM-UHFFFAOYSA-N

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應用

以对苯醌和四硫富瓦烯为介体,研究了自组装膜修饰电极制备酶电化学生物传感器的影响参数。可用于氨基酸、洗发水和药物混合物中半胱氨酸和/或羧甲司坦的分光光度测定。它也可作为过氧化物引发聚丙烯交联的有效催化剂。

其他說明

用于分光光度法检测微量胺的试剂

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Sol. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

170.6 °F - closed cup

閃點(°C)

77 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Spectrophotometric microdetermination of amines and sulfamates with 1,4-Benzoquinone.
G A Benson et al.
Analytical chemistry, 48(14), 2149-2152 (1976-12-01)
Preparation, characterization and application of alkanethiol self-assembled monolayers modified with tetrathiafulvalene and glucose oxidase at a gold disk electrode.
Campuzano S
Journal of Electroanalytical Chemistry, 526 (1), 92-100 (2002)
Peroxide-initiated crosslinking of polypropylene in the presence of p-benzoquinone.
Chodak I and Lazar M.
Journal of Polymer Science: Part A, General Papers, 32 (6), 5432-5437 (1986)
D A Zaia et al.
Talanta, 50(5), 1003-1010 (2008-10-31)
A simple, sensitive, and selective method has been developed for determination of cysteine (Cys) or carbocysteine (carboCys) in pharmaceutical products, shampoos and a mixture of amino acids. The results showed the reaction between p-benzoquinone (PBQ) and Cys occurs through the
Vandana Bhalla et al.
Dalton transactions (Cambridge, England : 2003), 42(4), 975-980 (2012-11-21)
A pentaquinone based compound 3a has been synthesized which undergoes significant fluorescence enhancement in the presence of Zn(2+) ions with a detection limit up to nanomolar range in THF. Further, the zinc ensemble of 3a is evaluated for its anti-oxidizing

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