推荐产品
蒸汽密度
9 (vs air)
品質等級
化驗
97%
自燃溫度
392 °F
反應適用性
reagent type: ligand
reaction type: Acetylations
reagent type: ligand
reaction type: Addition Reactions
reagent type: ligand
reaction type: Stille Coupling
折射率
n20/D 1.462 (lit.)
bp
150 °C/50 mmHg (lit.)
密度
0.81 g/mL at 25 °C (lit.)
官能基
phosphine
SMILES 字串
CCCCP(CCCC)CCCC
InChI
1S/C12H27P/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
InChI 密鑰
TUQOTMZNTHZOKS-UHFFFAOYSA-N
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應用
1,4-加成催化剂；与二硫化物一起用于醇的硫醚化反应；酰化催化剂；用于制备活性酯。
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1A
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
WGK 2
閃點（°F）
242.6 °F - closed cup
閃點（°C）
117 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Solvent effects on hydrogen bonding.
Joanne L Cook et al.
Angewandte Chemie (International ed. in English), 46(20), 3706-3709 (2007-04-07)
Bradley G Jellerichs et al.
Journal of the American Chemical Society, 125(26), 7758-7759 (2003-06-26)
Upon exposure of mono-enone mono-allylic carbonates to tributylphosphine and 1 mol % Pd(Ph3P)4, efficient conversion to the corresponding cycloallylated products is achieved. This transformation combines the nucleophilic features of the Morita-Baylis-Hillman reaction with the electrophilic features of the Trost-Tsuji reaction.
J Krijt et al.
Clinical chemistry, 47(10), 1821-1828 (2001-09-25)
Aminothiols have been implicated in the pathogenesis of arteriosclerosis, and reliable methods are needed to determine their concentrations in body fluids. We present a comparison of two analytical methods and focus on the reduction of low-molecular weight and protein-mixed disulfides
J X Yan et al.
Journal of chromatography. A, 813(1), 187-200 (1998-08-11)
A simple technique is introduced to identify and quantitate cysteine (Cys) after acid hydrolysis of protein. The technique involves using 9-fluorenylmethyl chloroformate (Fmoc)-based amino acid analysis that recovers all of the amino acids (asparagine and glutamine are recovered in their
Jing-Yu Wu et al.
The Journal of organic chemistry, 73(22), 9137-9139 (2008-10-24)
Aziridines underwent cyclization reaction with carbon disulfide and isothiocyanate in the presence of organophosphine to afford thiazolidinone derivatives in good to high yields. The mechanistic study revealed that organophosphine serves as a catalyst in the reaction.
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