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  • Tributylphosphine-catalyzed cycloaddition of aziridines with carbon disulfide and isothiocyanate.

Tributylphosphine-catalyzed cycloaddition of aziridines with carbon disulfide and isothiocyanate.

The Journal of organic chemistry (2008-10-24)
Jing-Yu Wu, Zhi-Bin Luo, Li-Xin Dai, Xue-Long Hou
摘要

Aziridines underwent cyclization reaction with carbon disulfide and isothiocyanate in the presence of organophosphine to afford thiazolidinone derivatives in good to high yields. The mechanistic study revealed that organophosphine serves as a catalyst in the reaction.

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Sigma-Aldrich
三丁基膦, ≥93.5% (Tri-N-butylphosphine, GC)
Sigma-Aldrich
三丁基膦, mixture of isomers, 97%
Sigma-Aldrich
三正丁基膦, 99%
Sigma-Aldrich
三正丁基膦, 97%
Sigma-Aldrich
三丁基膦 溶液, 200 mM (in N-methyl-2-pyrrolidinone), liquid