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M72609

Sigma-Aldrich

N-甲基哌啶

99%

别名:

1-甲基哌啶

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About This Item

经验公式（希尔记法）:
C6H13N
CAS号:
626-67-5
分子量:
99.17
Beilstein:
1073
EC號碼:
210-959-9
MDL號碼:
MFCD00006491
分類程式碼代碼:
12352100
PubChem物質ID:
24897150
NACRES:
NA.22

品質等級

200

化驗

99%

折射率

n20/D 1.4378 (lit.)

bp

106-107 °C (lit.)

密度

0.816 g/mL at 25 °C (lit.)

SMILES 字串

CN1CCCCC1

InChI

1S/C6H13N/c1-7-5-3-2-4-6-7/h2-6H2,1H3

InChI 密鑰

PAMIQIKDUOTOBW-UHFFFAOYSA-N

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應用

反应物用于：
  • sp3 C-H 键通过钌 (II) 催化剂与环胺 C (3) 烷基化反应活化
  • Z-肉桂酸的一锅法合成

用于合成以下物质的反应物：
  • 不对称尿素酶
  • 抗菌咪唑、吡咯烷和哌啶盐
  • 通过钯催化的有机锡硫代酯偶联反应，得到角化酶A的C1-C16片段
  • 胰岛素样生长因子-1 受体和 ErbB 家族受体激酶的多靶点抑制剂

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

37.4 °F - closed cup

閃點（°C）

3 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
STBK1016
STBG7402
STBF0309V
STBC2635V
STBB6235V

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Shahid Ullah et al.
Journal of chromatography. A, 1218(37), 6388-6395 (2011-07-28)
A trace analytical method based on high performance liquid chromatography coupled to quadrupole time-of-flight high resolution mass spectrometry was developed for simultaneous determination of perfluoroalkyl phosphonates (PFPAs, carbon chain lengths C6,8,10), perfluoroalkyl carboxylates (PFCAs, C5-12), and perfluoroalkyl sulfonates (PFSAs, C4,6,8,10)
[Studies of pyrazine derivatives. XXV. Synthesis and the tuberculostatic activity of the products of reaction of 5-(6-methoxy- and 5-(6 morpholinopyrazinyl)-1,3,4-oxadiazol-2-thione with amines].
D Pancechowska-Ksepko et al.
Acta poloniae pharmaceutica, 45(5), 373-379 (1988-01-01)
N D Henderson et al.
Anti-cancer drug design, 11(6), 421-438 (1996-09-01)
Bioreducible anti-tumour agents are prodrugs which are intended to be inactive in normal cells, but are able to undergo metabolic reduction in cancer cells to produce toxic species that can damage biomolecules. A series of N-oxides of heterocyclic aliphatic amines
Francisc Potmischil et al.
Magnetic resonance in chemistry : MRC, 45(3), 231-235 (2007-01-16)
The (15)N chemical shifts of 13 N-methylpiperidine-derived mono-, bi- and tricycloaliphatic tertiary amines, their methiodides and their N-epimeric pairs of N-oxides were measured, and the contributions of specific structural parameters to the chemical shifts were determined by multilinear regression analysis.
A Kolocouris et al.
The Journal of organic chemistry, 66(15), 4989-4997 (2001-07-21)
When a 1-adamantyl or a 2-adamantyl substituent is introduced at the 2-position in N-methylpiperidine, four different chair conformations are possible. Experimental observation using dynamic NMR spectroscopy and molecular mechanics calculations agree that the chair conformation with an equatorial adamantyl group
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