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Merck

M56557

Sigma-Aldrich

4-甲基吗啉

ReagentPlus®, 99%

别名:

N -甲基吗啉, NMM

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About This Item

经验公式(希尔记法):
C5H11NO
CAS号:
分子量:
101.15
Beilstein:
102719
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
bp:
115-116 °C/750 mmHg (lit.)

等級

reagent

品質等級

蒸汽密度

>1 (vs air)

蒸汽壓力

18 mmHg ( 20 °C)

產品線

ReagentPlus®

化驗

99%

形狀

liquid

dilution

(for general lab use)

折射率

n20/D 1.435 (lit.)

bp

115-116 °C/750 mmHg (lit.)

mp

−66 °C (lit.)

密度

0.92 g/mL at 25 °C (lit.)

SMILES 字串

CN1CCOCC1

InChI

1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3

InChI 密鑰

SJRJJKPEHAURKC-UHFFFAOYSA-N

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一般說明

4-methylmorpholine, also known as N-Methylmorpholine, is a cyclic tertiary amine and is commonly used as a highly valuable solvent and a fine chemical for cellulose.

應用

4-甲基吗啉可用于通过与溴丁烷反应合成 N -丁基- N -甲基吗啉溴。
4-methylmorpholine is used:
  • in the synthesis of N-methylmorpholine-N-oxide (NMMO)
  • as an effective and inexpensive additive for highly enantioselective arylation of aryl aldehydes catalyzed by the (S)-H8-BINOL-Ti(Oi-Pr)2 complex

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

53.6 °F - closed cup - DIN 51755 Part 1

閃點(°C)

12 °C - closed cup - DIN 51755 Part 1

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Size-controlled electrochemical synthesis of palladium nanoparticles using morpholinium ionic liquid.
Cha J H, et al.
Korean Journal of Chemical Engineering, 24(6), 1089-1094 (2007)
Christopher N Cultrara et al.
Molecular therapy. Nucleic acids, 18, 863-870 (2019-11-19)
Oligoarginine sequences conjugated to a short cancer-targeting peptide (CTP) selective for the prostate-specific membrane antigen (PSMA) receptor was developed for selective small interfering RNA (siRNA) delivery to a human metastatic/castration-resistant prostate cancer (PCa) cell line, which expresses PSMA on the
Benedetta Del Secco et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 18(9), 2142-2149 (2019-04-24)
Silica nanoparticles (NPs) are versatile nanomaterials, which are safe with respect to biomedical applications, and therefore are highly investigated. The advantages of NPs include their ease of preparation, inexpensive starting materials and the possibility of functionalization or loading with various
L Belin et al.
British journal of industrial medicine, 40(3), 251-257 (1983-08-01)
Investigations of respiratory symptoms among workers in a factory producing polyurethane foam included measurement of air pollution with amines and isocyanates and a simultaneous health investigation of the exposed workers. An increased bronchial reactivity to inhaled methacholine was found in
V Balachandran et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 1101-1110 (2012-08-30)
The experimental FT-IR (4000-400 cm(-1)) and FT-Raman (3500-100 cm(-1)) spectra of 4-Methylmorpholine were recorded. The observed bands were interpreted with the aid of normal coordinate analysis and force field calculations based on density functional theory (DFT) using B3LYP functional theory

Global Trade Item Number

货号GTIN
M56557-100ML4061834060185
M56557-500ML4061834060192
M56557-5ML

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