CF0004

Alcohol Togni-(PhSCF₂CF₂)-reagent

• 线性分子式: C₁₇H₁₅F₄IOS
• CAS号: 1836233-11-4
• MDL號碼: MFCD31618525
• 分類程式碼代碼: 12352200

属性

• 形狀: solid
• 反應適用性: reaction type: C-C Bond Formation
• 儲存溫度: −20°C

说明

應用

Alcohol Togni-(PhSCF₂CF₂)-reagent is an electrophilic hypervalent iodine-fluoroalkyl reagent introducing the phenylsulfanyltetrafluoroethyl fragment. A phenylsulfanyltetrafluoroethyl moiety incorporated in the substrate can be treated with tributyltin hydride and generate the corresponding fluoroalkyl radical. If the substrate lacks any olefine, it can be reduced to tetrafluoroethyl group whereas if the substrate contains an olefine in the correct spatial orientation, it can lead to an intramolecular cyclisation affording tetrafluorinated cyclic structures.

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其他說明

Technology Spotlight: Fluoroalkylation: Expansion of Togni Reagents

法律資訊

Product of CF Plus Chemicals.

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable