922722

O-Pivaloylhydroxyamine triflic acid

• 别名: 2,2-dimethyl-, azanyl ester, 1,1,1-trifluoromethanesulfonate, PivONH₃OTF, Propanoic acid
• 经验公式（希尔记法）: C₅H₁₁NO₂ · CHF₃O₃S
• CAS号: 1293990-73-4
• 分子量: 267.22
• 分類程式碼代碼: 12352106
• NACRES: NA.22

属性

• 形狀: solid
• 品質等級: 100
• 官能基: fluoro; triflate

说明

應用

This hydroxylamine-based reagent enables the iron-catalyzed selective transformation of thiols to sulfinamides under mild conditions without the use of precious metal catalysts or additional oxidants. This reagent is shelf stable and facilitates the reaction in a single step and under mild conditions.

其他說明

Hydroxylamine-Derived Reagent as a Dual Oxidant and Amino Group Donor for the Iron Catalyzed Preparation of Unprotected Sulfinamides from Thiols

Synthesis of N-Alkyl Anilines from Arenes via Iron-Promoted Aromatic C–H Amination

安全信息

• 象形圖: GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H302,H314,H335
• 防範說明: P260 - P271 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 8A - Combustible corrosive hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable