913014

[1,3-Bis(diphenylphosphino)propane]dibromonickel(II)

≥95%

• 别名: Ni(dppp)Br₂
• 经验公式（希尔记法）: C₂₇H₂₆Br₂NiP₂
• CAS号: 15629-93-3
• 分子量: 630.94
• 分類程式碼代碼: 12352101

属性

• 化驗: ≥95%
• 形狀: powder
• 反應適用性: reagent type: catalyst; reaction type: Cross Couplings
• mp: >300 °C

说明

應用

[1,3-Bis(diphenylphosphino)propane]dibromonickel(II) is catalyst for:

• Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
• Solid state metathesis polycondensation
• Polymerization of poly(3-alkoxythiophene)s
• Double bond isomerization

其他說明

Double-Bond Isomerization: Highly Reactive Nickel Catalyst Applied in the Synthesis of the Pheromone (9Z,12Z)-Tetradeca-9,12-dienyl Acetate

安全信息

• 象形圖: GHS08,GHS09
• 訊號詞: Danger
• 危險聲明: H317,H334,H341,H350i,H360D,H372,H410
• 防範說明: P201 - P273 - P280 - P302 + P352 - P308 + P313
• 危險分類: Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable