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化驗
≥95%
形狀
powder
反應適用性
reagent type: catalyst
reaction type: Cross Couplings
mp
322-326 °C
InChI
1S/C26H24P2.2BrH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChI 密鑰
AEGMSHMBRVOLMV-UHFFFAOYSA-L
相关类别
應用
[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II) is a catalyst for a variety of transformations, including:
- kumada catalyst-transfer polycondensation
- oxidation of carboranyl phosphine ligands
- synthesis of nickel-iron dithiolato hydrides
- hydroformylation of alcohols
- Ullmann reactions - homocoupling reactions
- intramolecular aerobic oxidative amination of alkenes
相關產品
产品编号
说明
价格
訊號詞
Danger
危險分類
Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Chuan-Che Liu et al.
Organic letters, 12(15), 3518-3521 (2010-07-09)
An efficient method for the synthesis of substituted 1(2H)-isoquinolone derivatives via nickel-catalyzed annulation of substituted 2-halobenzamides with alkynes is described. This protocol is successfully applied to the total synthesis of oxyavicine with excellent yield.
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