911402

(CyPAd-DalPhos)NiCl(otol)

≥95%

• 别名: 8-(2-(Dicyclohexylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane nickel(II) o-tolyl chloride
• 经验公式（希尔记法）: C₃₅H₄₉ClNiO₃P₂
• CAS号: 2115838-60-1
• 分子量: 673.86
• MDL號碼: MFCD32205518
• 分類程式碼代碼: 12352200
• NACRES: NA.22

属性

• 化驗: ≥95%
• 形狀: powder
• 反應適用性: reagent type: catalyst; reaction type: Cross Couplings
• mp: 193-197 °C

说明

應用

(CyPAd-DalPhos)NiCl(otol) is an air stable precatalyst developed in the Stradiotto lab used for C(sp²)-O coupling and N-arylation reactions.

其他說明

Technology Spotlight: DalPhos ligands

Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols

Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature

安全信息

• 象形圖: GHS08,GHS07,GHS09
• 訊號詞: Danger
• 危險聲明: H302 + H312 + H332,H341,H351,H372,H410
• 防範說明: P201 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P308 + P313
• 危險分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - STOT RE 1 Inhalation
• 標靶器官: Respiratory Tract,Skin
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable