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Merck

804959

Sigma-Aldrich

DavePhos-Pd-G3

95%

别名:

甲烷磺酸-2-二环己基膦基-2-(N,N-二甲胺基)联苯基(′-氨基-1,1′-联苯-2-基)钯(II)

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About This Item

经验公式(希尔记法):
C39H49N2O3PPdS
分子量:
763.28
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

95%

形狀

solid

特點

generation 3

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

雜質

<5% THF

mp

183-200 °C (decomp)

官能基

phosphine

SMILES 字串

CN(C)C1=C(C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2)C=CC=C1.NC5=C(C6=C([Pd]OS(C)(=O)=O)C=CC=C6)C=CC=C5

InChI

1S/C26H36NP.C12H10N.CH4O3S.Pd/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-12,17-22H,3-8,13-16H2,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI 密鑰

FBIRGVXUSGLNQE-UHFFFAOYSA-M

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相关类别

一般說明

DavePhos-Pd-G3是经过修饰的G3预催化剂(G3′)。Buchwald及其同事采用第二代(G2)预催化剂通过联苯主链上氨基的甲基化作用合成了它。它是各种交叉偶联反应的催化剂。它们是多功能的催化剂。它们在溶液中的使用寿命很长,并且易溶于各种有机溶剂。G3预催化剂已被用于各种C-N键形成反应。

應用

用于交叉偶联的 Pd 预催化剂

象形圖

Health hazard

訊號詞

Warning

危險聲明

危險分類

Carc. 2

安全危害

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析证书(COA)

Lot/Batch Number

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2-Aminobiphenyl Palladacycles: The ?Most Powerful? Precatalysts in C-C and C-Heteroatom Cross-Couplings.
Bruneau A, et al.
ACS Catalysis, 5(2), 1386-1396 (2015)

商品

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.

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