795674

3-(Trimethylsilyl)pyridin-2-yl trifluoromethanesulfonate

95%

• 别名: Garg 2,3-pyridyne precursor
• 经验公式（希尔记法）: C₉H₁₂F₃NO₃SSi
• CAS号: 134391-76-7
• 分子量: 299.34
• MDL號碼: MFCD18257067
• 分類程式碼代碼: 12352100
• PubChem物質ID: 329768501
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: 95%
• 形狀: liquid
• 折射率: n/D 1.454
• 密度: 1.266 at 25 °C
• 官能基: fluoro; triflate
• 儲存溫度: 2-8°C
• InChI: 1S/C9H12F3NO3SSi/c1-18(2,3)7-5-4-6-13-8(7)16-17(14,15)9(10,11)12/h4-6H,1-3H3
• InChI 密鑰: SXIBFUWSBRRXRJ-UHFFFAOYSA-N

说明

應用

Pyridyne precursor can be activated under mild fluoride conditions; which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.

其他說明

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions

Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model

安全信息

• 象形圖: GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H315,H318,H335
• 防範說明: P280 - P302 + P352 - P305 + P351 + P338 + P310
• 危險分類: Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable