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709042

Sigma-Aldrich

[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]氯[3-苯基烯丙基]钯(II)

Umicore, 95%

别名:

CX 31

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About This Item

经验公式（希尔记法）:
C36H45ClN2Pd
CAS号:
884879-23-6
分子量:
647.63
MDL號碼:
MFCD11045095
分類程式碼代碼:
12161600
PubChem物質ID:
329762845
NACRES:
NA.22

品質等級

100

化驗

95%

形狀

powder

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

205-208 °C

SMILES 字串

[CH2][CH][CH]c1ccccc1.CC(C)c2cccc(C(C)C)c2N3C=CN(\C3=[Pd]/Cl)c4c(cccc4C(C)C)C(C)C

InChI

1S/C27H36N2.C9H9.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-2-6-9-7-4-3-5-8-9;;/h9-16,18-21H,1-8H3;2-8H,1H2;1H;/q;;;+1/p-1

InChI 密鑰

RWGNZUQSYXTZIX-UHFFFAOYSA-M

相关类别

應用

  • Catalyst for Suzuki coupling (eq. 1)
  • Catalyst for Buchwald-Hartwig amination reaction (eq. 2)
Catalyst for:
  • Suzuki-Miyaura couplings
  • Buchwald-Hartwig couplings

法律資訊

Product of Umicore

Additional information available at www.pmc.umicore.com

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Oscar Navarro et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(19), 5142-5148 (2006-04-22)
The use of second-generation [(NHC)Pd(R-allyl)Cl] complexes for Suzuki-Miyaura and Buchwald-Hartwig cross-coupling reactions involving heteroaromatic halides at room temperature is reported. The first examples of room temperature Suzuki-Miyaura cross-coupling of deactivated aryl chlorides with alkenyl boronic acids are also disclosed. Terminal
Nicolas Marion et al.
Journal of the American Chemical Society, 128(12), 4101-4111 (2006-03-23)
A series of (NHC)Pd(R-allyl)Cl complexes [NHC: IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, SIPr = N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene; R = H, Me, gem-Me2, Ph] have been synthesized and fully characterized. When compared to (NHC)Pd(allyl)Cl, substitution at the terminal position of the allyl scaffold favors a more
Bruce H Lipshutz et al.
Organic letters, 10(7), 1333-1336 (2008-03-14)
Use of a dilute aqueous solution containing a nonionic amphiphile allows efficient Suzuki-Miyaura cross-couplings of arylboronic acids with a wide array of aryl halides and pseudohalides, including sterically hindered and lipophilic substrates, in most cases at room temperature.

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