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Merck

681482

Sigma-Aldrich

2-(烯丙基二甲基甲硅烷基)吡啶

90%

别名:

烯丙基二甲基(2-吡啶基)硅烷

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About This Item

线性分子式:
(CH2CHCH2)Si(CH3)2(C5H4N)
分子量:
177.32
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

化驗

90%

折射率

n20/D 1.5046

密度

0.913 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

C[Si](C)(CC=C)c1ccccn1

InChI

1S/C10H15NSi/c1-4-9-12(2,3)10-7-5-6-8-11-10/h4-8H,1,9H2,2-3H3

InChI 密鑰

WIRIPVDRZYVTCG-UHFFFAOYSA-N

應用

2-(Allyldimethylsilyl)pyridine can be used as a pyridyl transfer reagent to prepare substituted pyridine derivatives by reacting with various aryl iodides in the presence of a palladium catalyst and silver(I) oxide activator. It can also be utilized as a coupling reagent in the allylation of carbonyl compounds using a copper catalyst.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

160.0 °F - closed cup

閃點(°C)

71.1 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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Toshiki Nokami et al.
Organic letters, 8(4), 729-731 (2006-02-14)
[reaction: see text] (2-Pyridyl)allyldimethylsilanes were found to be novel pyridyl transfer reagents in palladium-catalyzed cross-coupling reactions of various aryl iodides in the presence of silver(I) oxide as an activator.
Copper-catalyzed allylation of carbonyl derivatives using allyl (2-pyridyl) silanes
Kamei T, et al.
Organic Letters, 7(21), 4725-4728 (2005)

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