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About This Item
经验公式（希尔记法）:
C32H22O2
CAS号:
分子量:
438.52
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22
推荐产品
品質等級
化驗
97%
光學活性
[α]20/D -314°, c = 1 in chloroform
mp
199-203 °C
官能基
phenyl
SMILES 字串
Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6
InChI
1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H
InChI 密鑰
NDTDVKKGYBULHF-UHFFFAOYSA-N
應用
(S)-VANOL 是一种拱形联芳基配体，可用于合成配位配合物，例如（dppe）Pt（S-VANOL）[dppe =双（二苯基膦基）乙烷]和（S,S-chiraphos）Pt （S-VANOL）[Chiraphos＝2，3-双（二苯基膦基）丁烷]。
VANOL 已被证明是催化不对称 Diels-Alder、亚胺羟醛和叠氮化反应的出色配体。
訊號詞
Danger
危險分類
Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Synthesis and characterization of chiral diphosphine platinum (II) VANOL and VAPOL complexes.
Becker JJ, et al.
Organometallics, 22(16), 3245-3249 (2003)
Bao. J. et al.
Journal of the American Chemical Society, 118, 3392-3392 (1996)
Su Yu et al.
Organic letters, 7(3), 367-369 (2005-01-28)
[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carboxamide via the method of Snieckus.
Yu Zhang et al.
Organic letters, 5(11), 1813-1816 (2003-05-24)
[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ generation of copper(II) and leads to the reproducible formation of
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