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Merck

634565

Sigma-Aldrich

高氯酸锂

greener alternative

battery grade, dry, 99.99% trace metals basis

别名:

高氯酸,锂盐

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About This Item

线性分子式:
LiClO4
CAS号:
分子量:
106.39
EC號碼:
MDL號碼:
分類程式碼代碼:
26111700
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

99.99% trace metals basis

形狀

powder and chunks

反應適用性

reagent type: oxidant

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

236 °C (lit.)

溶解度

H2O: 106.4 g/L at 20 °C

應用

battery manufacturing

環保替代類別

SMILES 字串

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI 密鑰

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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一般說明

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了能源效率。点击此处,查看更多详情。
高氯酸锂 (LiClO 4 ) 是一种高溶解度的中性盐。LiClO 4 可用作锂硫电池的电解液;它已被证明能有效抑制化学多硫化物穿梭,随后通过充电过程提高柱状效率。
高氯酸锂是一类电解材料,可用于制造锂离子电池。锂离子电池由具有充放电循环的阳极、阴极和电解液组成。这些材料能形成更环保的可持续性电能储存电池。

應用

LiClO 4 用作锂硫电池的电解质盐。LiClO 4 在环氧化物的无溶剂硫解中作为催化剂。它被用于各种有机转化。
LiClO4可作为添加剂,用于制备高性能聚偏二氟乙烯(PVDF)纤维膜。也可以掺入壳聚糖和淀粉,用于制造超级电容器。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

5.1A - Strongly oxidizing hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

Lot/Batch Number

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Shuttle inhibitor effect of lithium perchlorate as an electrolyte salt for lithium-sulfur batteries
Kim HS, et al.
J. Appl. Electrochem., 42(2) (2012)
Lithium perchlorate doped plasticized chitosan and starch blend as biodegradable polymer electrolyte for supercapacitors
Sudhakar YN and Selvakumar M
Electrochimica Acta, 78, 398-405 (2012)
Solvent-free thiolysis of epoxides under lithium perchlorate catalysis.
Mojtahedi M, et al.
Monatshefte fur Chemie / Chemical Monthly, 137(4), 455-458 (2006)
Preparation of porous PVDF hollow fibre membrane via a phase inversion method using lithium perchlorate (LiClO4) as an additive
Yeow ML, et al.
Journal of Membrane Science , 258(1-2), 16-22 (2005)
Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave

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