532126

[rac-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)

97%

• 别名: Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium
• 经验公式（希尔记法）: C₂₀H₂₄Cl₂Zr
• CAS号: 100163-29-9
• 分子量: 426.53
• MDL號碼: MFCD00672123
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24877859
• NACRES: NA.22

属性

• 化驗: 97%
• 反應適用性: core: zirconium; reagent type: catalyst
• mp: 267-271 °C (lit.)
• SMILES 字串: Cl[Zr]Cl.[CH]1[CH][C](CC[C]2[CH][CH][C]3CCCC[C]23)[C]4CCCC[C]14
• InChI: 1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
• InChI 密鑰: AKXWJOYQORUUHS-UHFFFAOYSA-L

说明

應用

Catalyst for:

• Regiochemistry in Negishi carboaluminations
• Polymerization of olefins
• Diastereoselective intramolecular olefin alkylations
• Asymmetric carbomagnesiation
• Reduction of esters to alcohols
• Enantioselective synthesis of allylic amines

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves