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Merck

482358

Sigma-Aldrich

四氟硼酸二铁

technical grade

别名:

双(环戊二烯基)四氟硼酸铁, 四氟硼酸二环戊二烯基铁, 氟硼酸二环戊二烯基铁

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About This Item

经验公式(希尔记法):
C10H10BF4Fe
CAS号:
分子量:
272.84
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

反應適用性

core: iron
reagent type: catalyst

mp

178 °C (dec.) (lit.)

SMILES 字串

[Fe+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.BF4.Fe/c2*1-2-4-5-3-1;2-1(3,4)5;/h2*1-5H;;/q;;-1;+1

InChI 密鑰

ZSPXIHLQPWVOQR-UHFFFAOYSA-N

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一般說明

四氟硼酸二茂铁[FeCp2][BF4]是化学合成中常用的二茂铁盐之一。二茂铁盐通常用作路易斯酸催化剂、单电子氧化剂和电子供体。

應用

四氟硼酸二茂铁可用作:

  • 合成单阳离子Co(II)配合物[CpCo(azpy)]+的氧化剂
  • 环氧化物开环和活化羰基进行加成或环加成反应中的路易斯酸催化剂
  • 与Cl-源一起使用时的氧化剂
  • 锡唑二价阴离子与双锡唑-1,2-二价阴离子之间的可逆氧化还原试剂

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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R F Anderson et al.
The Journal of biological chemistry, 275(40), 30781-30786 (2000-06-22)
Trimethylamine dehydrogenase from the pseudomonad Methylophilus methylotrophus has been examined using the technique of pulse radiolysis to rapidly introduce a single reducing equivalent into the enzyme. Using enzyme that has had its iron-sulfur center rendered redox-inert by prior reaction with
Ralf Warratz et al.
Inorganic chemistry, 48(8), 3591-3607 (2009-03-27)
Ferrocene-ferrocenium dimers exhibit a double-peak intervalence charge-transfer (IVCT) band in the NIR/MIR region, which is analyzed in terms of a four-level, two-mode vibronic coupling configuration interaction (VCCI) scheme. Besides providing satisfactory fits of the measured spectra, the model also gives
T David Harris et al.
Chemical communications (Cambridge, England), 47(22), 6344-6346 (2011-05-07)
Oxidation of the nominally all-ferrous hexanuclear cluster ((H)L)(2)Fe(6) with six equivalents of ferrocenium in the presence of bromide ions results in a six-electron oxidation of the Fe(6) core to afford the nominally all-ferric cluster ((H)L)(2)Fe(6)Br(6). The hexabromide cluster is also
Songbo Xu et al.
Organic & biomolecular chemistry, 5(3), 558-568 (2007-01-26)
Various calix[4]arene derivatives, fixed in the cone conformation by decylether groups and functionalized at their wide rim by urea residues, were synthesized. In two compounds (,) sulfur functions were attached to the urea groups via different spacers in order to
Mutlu Sönmez Celebi et al.
Talanta, 78(2), 405-409 (2009-02-11)
A new surface based on poly(vinylferrocenium) (PVF(+))-modified platinum electrode was developed for determination of Hg(2+) ions in aqueous solutions. The polymer was electrodeposited on platinum electrode by constant potential electrolysis as PVF(+)ClO(4)(-). Cl(-) ions were then attached to the polymer

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