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Merck

119342

Sigma-Aldrich

(二甲基氨基甲基)二茂铁

≥95%

别名:

(二茂铁)二甲胺, N,N-二甲基二茂铁甲基胺, 二茂铁甲基胺

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About This Item

经验公式(希尔记法):
C13H17FeN
CAS号:
分子量:
243.13
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

化驗

≥95%

反應適用性

core: iron
reagent type: catalyst

折射率

n20/D 1.59 (lit.)

bp

124-128 °C/2.5 mmHg (lit.)

密度

1.228 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)C[C]2[CH][CH][CH][CH]2

InChI

1S/C8H12N.C5H5.Fe/c1-9(2)7-8-5-3-4-6-8;1-2-4-5-3-1;/h3-6H,7H2,1-2H3;1-5H;

InChI 密鑰

JJJSTEANRWLZBH-UHFFFAOYSA-N

一般說明

二甲基氨基甲基二茂铁(DMAMF)是一种二茂铁,由二甲基氨基甲基取代基连接其中一个配体而成。用作前体制备氧化铁膜。

應用

二甲基氨基甲基二茂铁用于:
  • 作为前体通过原子层沉积(ALD)制备氧化铁和镁掺杂氧化铁膜。
  • 作为胺配体用于合成五羰基(二甲基氨基甲基二茂铁)钨络合物。

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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V N Goral et al.
Biochemistry and molecular biology international, 45(1), 61-71 (1998-06-23)
Reactivity of horseradish peroxidase compounds I and II (HRP-I and HRP-II) toward organometallicic substrates, viz water-soluble ferrocenes RFc (R = COOH and CH2NMe2), has been studied at 25 degrees C, pH 6.0 and ionic strength 0.1 M. The second-order rate
S Takenaka et al.
Analytical biochemistry, 218(2), 436-443 (1994-05-01)
Electrochemically active DNA probes were prepared by linking a ferrocene unit with 5'-aminohexyl-terminated oligonucleotides. The DNA sequences of probes 5a, 5b, and 5c were 5'-T12-3', 5'-T20-3', and 5'-TGCAG TTCCG GTGGC TGATC-3', respectively. Probe 5a could form a complex selectively with
Guozhen Liu et al.
Analytica chimica acta, 909, 1-8 (2016-02-07)
A stable label-free amperometric immunosensor is presented based on gold nanoparticles and graphene oxide nanocomposites for detection of cardiac troponin-I in the early diagnosis of myocardial infarction. For designing of the sensing platform, firstly the nanocomposites based on GO and
Yoshihiro Kase et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 20(8), 1143-1146 (2004-09-09)
We propose an electron transfer-mediated amperometric enzyme biosensor based on plasma-polymerized thin film of dimethylaminomethylferrocene (DMAMF) on a sputtered gold electrode. The DMAMF plasma-polymerized film is deposited directly onto the surface of the electrode under dry conditions. The resulting thin
A N Shevel'kova et al.
Biokhimiia (Moscow, Russia), 58(6), 928-937 (1993-06-01)
The effects of dimethylaminomethylferrocene (DMAMF) on amylose and maltodextrins destruction by gluco-, alpha- and beta-amylases have been studied. The nature of DMAMF effects depends on the action mechanism of amylases and structure of their active sites. The effect observed is

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