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47638

Sigma-Aldrich

Fmoc-Val-OH

≥98.0% (HPLC)

别名:

N-(9-芴甲氧羰基)-L-缬氨酸, Fmoc-L-缬氨酸

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About This Item

经验公式（希尔记法）:
C20H21NO4
CAS号:
68858-20-8
分子量:
339.39
Beilstein:
2177443
EC號碼:
272-515-0
MDL號碼:
MFCD00037124
分類程式碼代碼:
12352209
eCl@ss:
32160406
PubChem物質ID:
57651055
NACRES:
NA.26

化驗

≥98.0% (HPLC)

形狀

solid

光學活性

[α]20/D −17±1°, c = 1% in DMF

反應適用性

reaction type: C-H Activation
reaction type: Fmoc solid-phase peptide synthesis
reagent type: ligand
reaction type: Peptide Synthesis

mp

143-145 °C (lit.)
143-147 °C

應用

peptide synthesis

官能基

Fmoc
amine
carboxylic acid

儲存溫度

2-8°C

SMILES 字串

CC(C)[C@H](NC(=O)OCC1c2ccccc2-c3ccccc13)C(O)=O

InChI

1S/C20H21NO4/c1-12(2)18(19(22)23)21-20(24)25-11-17-15-9-5-3-7-13(15)14-8-4-6-10-16(14)17/h3-10,12,17-18H,11H2,1-2H3,(H,21,24)(H,22,23)/t18-/m0/s1

InChI 密鑰

UGNIYGNGCNXHTR-SFHVURJKSA-N

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相关类别

一般說明

Fmoc-Val-OH又称为Fmoc-L-缬氨酸, 在Fmoc固相法多肽合成中起多种作用。

應用

作为起始原料，Fmoc-Val-OH可用于：
  • 使用O-酰基异二肽(O-acyl isodipeptide)单元，合成含困难序列的五肽
  • 按backbone amide linker(BAL)策略通过Fmoc固相法合成多肽

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCH0882
BCCF6272
BCCD5745
BCCC4498
BCCB0388

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Rosanna Capparelli et al.
PloS one, 4(9), e7191-e7191 (2009-09-29)
Temporins are antimicrobial peptides secreted by the granular glands of the European red frog (Rana temporaria). They are 10-14 amino acid long polypeptides active prevalently against gram positive bacteria. This study shows that a synthetic temporin B analogue (TB-YK), acquires
Karthik Nadendla et al.
Molecular pharmaceutics, 16(7), 2922-2928 (2019-05-24)
We have previously described the photoactivated depot (PAD) approach for the light-stimulated release of therapeutic proteins such as insulin. The aim of this method is to release insulin from a shallow dermal depot in response to blood glucose information, using
Leixia Mei et al.
Organic & biomolecular chemistry, 17(4), 939-944 (2019-01-11)
We report the synthesis and self-assembly of fluorescent peptide amphiphiles (NBD-PA) composed of a fluorescent NBD probe and a peptide derivative VVAADD with a C12-alkyl-chain as the linker (NBD-C12-VVAADD). The self-assembly of NBD-PA formed beta-sheet structures at neutral pH in
Hong Cheng et al.
Biomaterials, 211, 14-24 (2019-05-12)
Targeted delivery of the drug to its therapeutically active site with low immunogenicity and system toxicity is critical for optimal tumor therapy. In this paper, exosomes as naturally-derived nano-sized membrane vesicles are engineered by chimeric peptide for plasma membrane and
Hong Cheng et al.
Macromolecular bioscience, 19(4), e1800410-e1800410 (2018-12-24)
In this paper, a self-delivery chimeric peptide PpIX-PEG8 -KVPRNQDWL is designed for photodynamic therapy (PDT) amplified immunotherapy against malignant melanoma. After self-assembly into nanoparticles (designated as PPMA), this self-delivery system shows high drug loading rate, good dispersion, and stability as
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