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折射率
n20/D 1.469 (lit.)
品質等級
bp
137-140 °C/0.5 mmHg (lit.)
密度
1.4 g/mL at 25 °C (lit.)
官能基
carbonate
hydroxyl
SMILES 字串
OCC1COC(=O)O1
InChI
1S/C4H6O4/c5-1-3-2-7-4(6)8-3/h3,5H,1-2H2
InChI 密鑰
JFMGYULNQJPJCY-UHFFFAOYSA-N
應用
4-(羟甲基)-1,3-二氧戊环-2-酮可用作结构单元以:
- 通过威廉姆森醚合成法与三溴丙烷-1-乙炔合成4-[(丙烷-2-乙烯-1-基氧基)甲基]-1,3-二氧戊环-2-酮(AGC)。
- 通过与含有邻苯二酰亚胺组成成分的环状碳酸酯的共聚合作用合成超支化聚醚。
- 通过与苯乙酰氯发生反应合成(2-氧代-1,3-二氧戊环-4-基)苯乙酸甲酯。
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 1
閃點(°F)
230.0 °F - closed cup
閃點(°C)
110 °C - closed cup
個人防護裝備
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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Polyurethanes with pendant hydroxyl groups: synthesis and characterization.
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Cyclic carbonates obtained by reactions of alkali metal carbonates with epihalohydrins.
Rokicki G and Kuran W.
Bulletin of the Chemical Society of Japan, 57(6), 1662-1666 (1984)
Converting wastes into added value products: from glycerol to glycerol carbonate, glycidol and epichlorohydrin using environmentally friendly synthetic routes.
Dibenedetto A, et al.
Tetrahedron, 67(6), 1308-1313 (2011)
Anuja Bhalkikar et al.
Journal of separation science, 39(23), 4484-4491 (2016-11-03)
An ion-moderated partition high-performance liquid chromatography method was developed for the separation and identification of common organic carbonates. The separation of organic carbonates was achieved on an ion exclusion column with an exchangeable hydrogen ion. An isocratic, aqueous mobile phase
Mario Pagliaro et al.
Angewandte Chemie (International ed. in English), 46(24), 4434-4440 (2007-05-02)
Today, industrial plants that produce glycerol are closing down and others are opening that use glycerol as a raw material, owing to the large surplus of glycerol formed as a by-product during the production of biodiesel. Research efforts to find
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