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423769

Sigma-Aldrich

α-乙烯基苯甲醇

97%

别名:

α-乙烯基苯甲醇, α-苯基烯丙基醇, (±)-1-苯基烯丙基醇, 1′-羟基烯丙基苯, 1-羟基-1-苯基-2-丙烯, 1-苯基-2-丙烯-1-醇, 3-苯基-3-羟基-1-丙烯, 苯基乙烯基甲醇

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About This Item

线性分子式:
C6H5CH(CH=CH2)OH
CAS号:
42273-76-7
分子量:
134.18
MDL號碼:
MFCD00093987
分類程式碼代碼:
12352100
PubChem物質ID:
24866527
NACRES:
NA.22

化驗

97%

形狀

liquid

折射率

n20/D 1.54 (lit.)

bp

101-102 °C/12 mmHg (lit.)

密度

1.021 g/mL at 25 °C (lit.)

官能基

hydroxyl
phenyl

SMILES 字串

OC(C=C)c1ccccc1

InChI

1S/C9H10O/c1-2-9(10)8-6-4-3-5-7-8/h2-7,9-10H,1H2

InChI 密鑰

MHHJQVRGRPHIMR-UHFFFAOYSA-N

相关类别

一般說明

α-乙烯基苄醇是一种烯丙醇衍生物。已经报道了使用新型三元催化剂体系催化其异构化反应。 已经报道了使用钨催化的不对称环氧化方法对外消旋α-乙烯基苄醇进行动力学拆分。 已经研究了在RuCl2(PPh3)3 催化剂存在下并且使用In(OAc)3作为共催化剂，α乙烯基苄醇和醛在离子液体中的偶联反应。 已经报道了在二氧化硅固载磺酸（SiO2–SO3H）催化剂催化下，甘油与α-乙烯基苄醇的醚化反应。

應用

α−乙烯基苄醇与醇反应，可合成肉桂基醚。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

201.2 °F - closed cup

閃點（°C）

94 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BGBC5206V
BGBC2575V
BGBB9807
BGBB7027
1428185V

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A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten-bishydroxamic acid complex at room temperature with the use of aqueous 30% H2O2 as oxidant
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