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Merck
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414522

Sigma-Aldrich

7-氧杂二环[4.1.0]庚-2-酮

98%

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About This Item

经验公式（希尔记法）:
C6H8O2
CAS号:
6705-49-3
分子量:
112.13
EC號碼:
229-751-4
MDL號碼:
MFCD00192371
分類程式碼代碼:
12352100
PubChem物質ID:
24865940
NACRES:
NA.22

品質等級

100

化驗

98%

形狀

liquid

折射率

n20/D 1.474 (lit.)

bp

76-78 °C/15 mmHg (lit.)

密度

1.13 g/mL at 25 °C (lit.)

官能基

ether
ketone

SMILES 字串

O=C1CCCC2OC12

InChI

1S/C6H8O2/c7-4-2-1-3-5-6(4)8-5/h5-6H,1-3H2

InChI 密鑰

QKOHEJBTNOEACF-UHFFFAOYSA-N

相关类别

一般說明

7-Oxabicyclo[4.1.0]heptan-2-one is one of the products formed during oxidation of cyclohexene by dendritic complexes. It has been reported as anticapsin analog.

應用

7-Oxabicyclo[4.1.0]heptan-2-one was employed as substrate to investigate the substrate specificity of purified recombinant NADPH-dependent 3-quinuclidinone reductases from Microbacterium luteolum JCM 9174 for the reductive reaction of ketones.

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

204.8 °F - closed cup

閃點（°C）

96.00 °C - closed cup

個人防護裝備

Eyeshields, Gloves

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分析证书(COA)

Lot/Batch Number
MKCC4051
01716JJ
04622AU
15803LS
06715MF

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Oxidation of cyclohexene by dendritic PAMAMSA-Mn (II) complexes.
Yang Z-W, et al.
J. Mol. Catal. A: Chem., 213(2), 169-176 (2004)
Kentaro Isotani et al.
Applied and environmental microbiology, 79(4), 1378-1384 (2012-12-25)
We used the resting-cell reaction to screen approximately 200 microorganisms for biocatalysts which reduce 3-quinuclidinone to optically pure (R)-(-)-3-quinuclidinol. Microbacterium luteolum JCM 9174 was selected as the most suitable organism. The genes encoding the protein products that reduced 3-quinuclidinone were

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