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Merck

C102504

Sigma-Aldrich

氧化环己烯

98%

别名:

1,2-环氧环己烷, 7-氧杂二环[4.1.0]庚烷

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About This Item

经验公式(希尔记法):
C6H10O
CAS号:
分子量:
98.14
Beilstein:
383568
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

98%

形狀

liquid

自燃溫度

703 °F

expl. lim.

12.36 %

折射率

n20/D 1.452 (lit.)

bp

129-130 °C (lit.)

密度

0.97 g/mL at 25 °C (lit.)

SMILES 字串

C1CCC2OC2C1

InChI

1S/C6H10O/c1-2-4-6-5(3-1)7-6/h5-6H,1-4H2

InChI 密鑰

ZWAJLVLEBYIOTI-UHFFFAOYSA-N

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應用

  • Polymeric carbon nitride with internal np homojunctions for efficient photocatalytic CO2 reduction coupled with cyclohexene oxidation:以氮化碳聚合物为催化剂,采用氧化环己烯进行CO2的光催化还原反应。CO2还原反应可解决环境问题,伴随的偶联反应可高效转化氧化环己烯(W Zhen et al., 2021)。

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析证书(COA)

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Youli Xiao et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(12), 3668-3678 (2005-04-14)
The intramolecular dinuclear zinc complexes generated in situ from the reaction of multidentate semi-azacrown ether ligands with Et(2)Zn, followed by treatment with an alcohol additive, were found to promote the copolymerization of CO(2) and cyclohexene oxide (CHO) with completely alternating
M Amedjkouh et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 7(20), 4368-4377 (2001-11-07)
Improved stereoselectivity has been obtained by using 2-lithium-1-methylimidazole, 2, as a replacement for lithium diisopropylamide (LDA) as a bulk base in catalytic deprotonations. The chiral lithium amide 6 of (1R,2S)-N-methyl-1-phenyl-2-pyrrolidinylpropanamine, 5, has been found to deprotonate cyclohexene oxide 3 in
Dongliang Chang et al.
Chemical communications (Cambridge, England), (8)(8), 960-961 (2003-05-15)
Hydrolysis of N-benzyloxycarbonyl-3,4-epoxy-pyrrolidine and cyclohexene oxide with the epoxide hydrolase of Sphingomonas sp. HXN-200, respectively, gave the corresponding vicinal trans-diols in high ee and yield, representing the first example of enantioselective hydrolysis of a meso-epoxide with a bacterial epoxide hydrolase.
Mario Seiss et al.
Dental materials : official publication of the Academy of Dental Materials, 23(1), 9-16 (2006-02-07)
In previous studies it could be demonstrated that methacrylic acid (MA) is an intermediate in the metabolism of unpolymerized dental comonomers, released from dental restorative materials. This study was performed to identify the possible dental material intermediate 2,3-epoxymethacrylic acid (2,3-EMA)
Keiji Morokuma
Philosophical transactions. Series A, Mathematical, physical, and engineering sciences, 360(1795), 1149-1164 (2003-06-14)
As quantum chemistry plays a more and more central role in many complicated chemical problems, it has become necessary to obtain accurate results for large molecular systems. Conventional quantum chemistry methods are either too expensive to apply to large systems

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