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339768

Sigma-Aldrich

四乙腈四氟硼酸钯

别名:

NSC 307191, 四氟硼酸钯(II)-四乙腈复合物

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About This Item

线性分子式:
Pd(CH3CN)4(BF4)2
CAS号:
21797-13-7
分子量:
444.24
MDL號碼:
MFCD00043297
分類程式碼代碼:
12161600
PubChem物質ID:
24860675
NACRES:
NA.22

形狀

solid

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand

mp

230 °C (dec.) (lit.)

SMILES 字串

[Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F

InChI

1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2

InChI 密鑰

YWMRPVUMBTVUEX-UHFFFAOYSA-N

相关类别

一般說明

四（乙腈）钯 (II) 四氟硼酸盐是一种较强的路易斯酸。 参与薗头交叉偶联反应制备 2:1 配合物 [Pd（1,2-双（2′-吡啶乙炔基）苯）2](BF4]2。

應用

钯催化交叉偶联反应应用指南

反应物：
  • 由于弱配位乙腈配体而作为金属来源作用的反应

前体：
  • 树枝状 SCS-钳形钯配合物的合成
  • 短声配体钯配合物
  • 用于 Heck 交叉偶联 、Suzuki 交叉偶联和醛烯化反应的双钯催化剂

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H332

危險分類

Acute Tox. 4 Inhalation

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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分析证书(COA)

Lot/Batch Number
MKCP1032
MKCP1033
MKCL0304
MKCJ7330
MKCD4770

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Takashi Nishikata et al.
Journal of the American Chemical Society, 132(14), 4978-4979 (2010-03-24)
Cationic palladium(II) catalyst realized facile C-H activation of aryl urea with arylboronic acids at room temperature. This reaction is extremely mild to carry out aromatic C-H activations through electrophilic substitution.
Maud Reiter et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(27), 7190-7203 (2006-07-05)
Structurally diverse beta-hydroxyenones are shown to undergo nonoxidative 6-endo-trig ring closure to form highly substituted tetrahydropyranones. Amberlyst-15, Al(ClO(4))(3) x 9 H(2)O and [Pd(MeCN)(4)](BF(4))(2) were found to be suitable catalysts for these intramolecular conjugate additions, preventing side reactions, such as dehydration
Yun Fu Chan et al.
Dalton transactions (Cambridge, England : 2003), (32)(32), 3538-3545 (2007-08-08)
Extended-chain complexes containing multiple transition metal centres linked by conjugated micro-cyanodiazenido(1-) ligands [N=N-C[triple bond, length as m-dash]N]- have been obtained by reaction of trans-[BrW(dppe)2(N2CN)], , [dppe=1,2-bis(diphenylphosphino)ethane] with dirhodium(II) tetra-acetate, bis(benzonitrile)palladium(II) dichloride, and bis(aqua)M(II) bis(hexafluoroacetylacetonate) (M=Mn, Ni, Cu, Zn): stronger Lewis
Adam M Johns et al.
Journal of the American Chemical Society, 128(6), 1828-1839 (2006-02-09)
We report a catalyst for intermolecular hydroamination of vinylarenes that is substantially more active for this process than catalysts published previously. With this more reactive catalyst, we demonstrate that additions of amines to vinylarenes and dienes occur in the presence
Gorman, C. B.; Vest, R. W. et al.
Macromolecules, 32, 4157-4157 (1999)
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Heck Reaction

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

Heck Reaction

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

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