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About This Item
经验公式（希尔记法）:
Br2Pd
CAS号:
分子量:
266.23
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23
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品質等級
化驗
99%
形狀
powder
反應適用性
reagent type: catalyst
core: palladium
密度
5.173 g/mL at 25 °C (lit.)
SMILES 字串
Br[Pd]Br
InChI
1S/2BrH.Pd/h2*1H;/q;;+2/p-2
InChI 密鑰
INIOZDBICVTGEO-UHFFFAOYSA-L
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一般說明
溴化钯（II）（PdBr2）是一种广泛使用的Pd(II)催化剂。PdBr2可通过使钯金属与HNO3和HBr发生反应而制备。从钯金属和HBr进行PdBr2的电合成已被报道。
應用
溴化钯（II）（PdBr2）在多种偶联反应中已被用作Pd(0)预催化剂的来源。它也可作为催化剂用于芳基溴化物和乙烯基醚的羰基Heck偶联反应。
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
其他客户在看
Palladium (II) Bromide.
Mahoney SJ, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Johannes Schranck et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(16), 4827-4831 (2012-03-17)
Three COming together: The first carbonylative Heck coupling reaction of aryl bromides and vinyl ethers leading to 1-aryl-3-alkoxy-2-propen-1-ones has been established (see scheme). Based on this coupling methodology, a novel one-pot synthesis of aryl-substituted pyrazoles was also realized.
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The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.
The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.
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