推荐产品
化驗
≥99.0% (C)
反應適用性
core: iridium
reagent type: catalyst
mp
175 °C (dec.) (lit.)
SMILES 字串
[Ir+].c1ccncc1.F[P-](F)(F)(F)(F)F.C2CC=CCCC=C2.C3CCC(CC3)P(C4CCCCC4)C5CCCCC5
InChI
1S/C18H33P.C8H12.C5H5N.F6P.Ir/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;1-2-4-6-5-3-1;1-7(2,3,4,5)6;/h16-18H,1-15H2;1-2,7-8H,3-6H2;1-5H;;/q;;;-1;+1/b;2-1-,8-7-;;;
InChI 密鑰
UJXHUUQZACSUOG-KJWGIZLLSA-N
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包裝
无底玻璃瓶。内含物装在插入的融合锥内。
其他說明
烯烃均相氢化反应的催化剂
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
其他客户在看
Angewandte Chemie (International Edition in English), 99, 169-169 (1987)
Journal of the American Chemical Society, 104, 6994-6994 (1982)
Journal of the American Chemical Society, 127(13), 4763-4776 (2005-03-31)
A wide variety of diynols containing tertiary, secondary, and primary propargylic alcohols undergo a cycloisomerization reaction to form dienones and dienals in the presence of a catalytic amount of [CpRu(CH(3)CN)(3)]PF(6). The formation of five- and six-membered rings is possible using
Synlett, 2043-2043 (2005)
Stereoselective synthesis of Boc-protected cis and trans-4-trifluoromethylprolines by asymmetric hydrogenation reactions.
Angewandte Chemie (International ed. in English), 41(9), 1600-1602 (2002-05-03)
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