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品質等級
化驗
97%
折射率
n20/D 1.410 (lit.)
bp
164-166 °C (lit.)
密度
0.941 g/mL at 25 °C (lit.)
官能基
ether
SMILES 字串
CCCCC(OC)(OC)OC
InChI
1S/C8H18O3/c1-5-6-7-8(9-2,10-3)11-4/h5-7H2,1-4H3
InChI 密鑰
XUXVVQKJULMMKX-UHFFFAOYSA-N
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一般說明
Kinetics of unimolecular gas-phase elimination of trimethyl orthovalerate has been investigated.
應用
Trimethyl orthovalerate has been used in the preparation of:
- various 9-O-acyl derivatives of N-acetyl- and N-glycoloyl-neuraminic acid
- 2-methyl, 2-ethyl, 2-propyl and 2-butyl-3-benzimidazolyl-4(3H)-quinazolinones
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
107.6 °F - closed cup
閃點(°C)
42 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
The journal of physical chemistry. A, 114(12), 4203-4209 (2010-03-10)
The rates of gas-phase elimination of trimethyl orthovalerate and trimethyl orthochloroacetate have been determined in a static system, and the reaction Pyrex vessels have been deactivated with the product of decomposition of allyl bromide. The reactions are unimolecular and follow
A facile synthesis of new 3-(2-benzimidazolyl)-2-alkyl-4-(3H)-quinazolinones under microwave irradiation.
Tetrahedron, 59(26), 4757-4760 (2003)
Carbohydrate research, 167, 77-86 (1987-09-15)
Various 9-O-acyl derivatives of N-acetyl- and N-glycoloyl-neuraminic acid, and O-(5-acetamido-3,5-dideoxy-D-glycero-alpha- and beta-D-galacto-2-nonulopyranosylonic acid)-(2----6)-O-beta-D-galactopyranosyl-(1----4)-D-glucopyranose were regioselectively synthesized by use of ortho esters. In addition, 5-acetamido-4-O-acetyl-D-glycero-D-galacto-2-nonulopyranosonic acid was prepared starting from the benzyl and methyl esters of N-acetylneuraminic acid.
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