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Merck

254185

Sigma-Aldrich

溴化铜

99.999% trace metals basis

别名:

一溴化铜

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About This Item

线性分子式:
CuBr
CAS号:
分子量:
143.45
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

99.999% trace metals basis

形狀

powder

反應適用性

reagent type: catalyst
core: copper

雜質

≤15.0 ppm Trace Metal Analysis

mp

504 °C (lit.)

密度

4.71 g/mL at 25 °C (lit.)

應用

battery manufacturing

SMILES 字串

[Cu]Br

InChI

1S/BrH.Cu/h1H;/q;+1/p-1

InChI 密鑰

NKNDPYCGAZPOFS-UHFFFAOYSA-M

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一般說明

溴化亚铜(I)是一种淡绿色的无机抗磁性固体,具有像硫化锌一样的聚合结构。不溶于水,广泛应用于催化、纳米材料合成和太阳能电池等领域。

應用

溴化亚铜(I)可用于:
  • 作为有机太阳能电池(OSC)的溶液可加工空穴传输层(HTL)。CuBr可提高太阳能电池的能量转换效率。
  • 作为合成光致发光金属有机框架(MOF)的前体。
  • 合成高发光性三配位铜(I)配合物作为OLED的掺杂剂,其最大外部量子效率为21.3%。
  • 与配体作为催化剂在14种不同溶剂中进行叔烷基卤化物的原子转移自由基聚合(ATRP)反应,测定速率常数。
  • 分子内自由基陷阱辅助原子转移自由基偶联法合成大环聚合物。

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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访问文档库

Denissova I and Barriault L et al.
Handbook of Reagents for Organic Synthesis null
Carla Sardo et al.
International journal of pharmaceutics, 563, 347-357 (2019-04-03)
Sustained pulmonary delivery of tobramycin from microparticles composed of drug/polymer nanocomplexes offers several advantages against traditional delivery methods. Namely, in patients with cystic fibrosis, microparticle delivery can protect the tobramycin being delivered from strong mucoadhesive interactions, thus avoiding effects on
Thomas F Cooke et al.
Cell, 171(2), 427-439 (2017-10-07)
Parrot feathers contain red, orange, and yellow polyene pigments called psittacofulvins. Budgerigars are parrots that have been extensively bred for plumage traits during the last century, but the underlying genes are unknown. Here we use genome-wide association mapping and gene-expression
Fang Sun et al.
Nature communications, 7, 13437-13437 (2016-11-12)
Surface-enhanced Raman spectroscopy (SERS) is an ultrasensitive analytical technique with molecular specificity, making it an ideal candidate for therapeutic drug monitoring (TDM). However, in critical diagnostic media including blood, nonspecific protein adsorption coupled with weak surface affinities and small Raman
Xiao-Yan Tu et al.
Macromolecular bioscience, 18(7), e1800022-e1800022 (2018-05-11)
The cyclic brush polymers, due to the unique topological structure, have shown in the previous studies higher delivery efficacy than the bottlebrush analogues as carriers for drug and gene transfer. However, to the best of knowledge, the preparation of reduction-sensitive

商品

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

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实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

An article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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