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等級
technical grade
化驗
95%
形狀
liquid
折射率
n20/D 1.417 (lit.)
bp
75-76 °C/10 mmHg (lit.)
密度
1.09 g/mL at 25 °C (lit.)
官能基
amine
儲存溫度
2-8°C
SMILES 字串
COC(=O)C[N+]#[C-]
InChI
1S/C4H5NO2/c1-5-3-4(6)7-2/h3H2,2H3
InChI 密鑰
CRXFROMHHBMNAB-UHFFFAOYSA-N
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一般說明
异氰乙酸甲酯在固相儿茶酚-铜网络催化剂存在下与羰基化合物发生直接羟醛缩合反应生成相应的恶唑啉 。它还参与四组分 Ugi 缩合反应 。
應用
异氰乙酸甲酯已被用于铜催化的、非对映选择性合成恶唑啉类 。
訊號詞
Danger
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
183.2 °F - closed cup
閃點(°C)
84 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Tetrahedron Letters, 47, 8641-8641 (2006)
Chemistry, an Asian journal, 6(9), 2545-2549 (2011-07-14)
The development of a highly active solid-phase catechol-copper network catalyst for direct aldol reaction is described. The catalyst was prepared from an alkyl-chain-linked bis(catechol) and a copper(II) complex. The direct aldol reaction between carbonyl compounds (aldehydes and ketones) and methyl
Biotechnology and bioengineering, 69(4), 457-460 (2000-06-22)
The chemoenzymatic preparation of a nine-member Ugi condensation library is described. The carboxylic acid and amine precursors are based on 3-hydroxybutyrate and 4-amino-1-butanol, respectively, and have been acylated selectively using a variety of acyl donors catalyzed by porcine pancreatic lipase.
Biomacromolecules, 20(1), 90-101 (2018-06-06)
A Passerini three-component polymerization was performed for the synthesis of amphiphilic star-shaped block copolymers with hydrophobic cores and hydrophilic coronae. The degree of polymerization of the hydrophobic core was varied from 5 to 10 repeating units, and the side chain
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