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Merck

226076

Sigma-Aldrich

苯甲醛二甲缩醛

99%

别名:

α,α-二甲氧基甲苯

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About This Item

线性分子式:
C6H5CH(OCH3)2
CAS号:
分子量:
152.19
Beilstein:
2044501
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.493 (lit.)

bp

87-89 °C/18 mmHg (lit.)

密度

1.014 g/mL at 25 °C (lit.)

官能基

acetal
ether
phenyl

SMILES 字串

COC(OC)c1ccccc1

InChI

1S/C9H12O2/c1-10-9(11-2)8-6-4-3-5-7-8/h3-7,9H,1-2H3

InChI 密鑰

HEVMDQBCAHEHDY-UHFFFAOYSA-N

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一般說明

研究了活性溴在80°下从苯甲醛二甲缩醛中萃取α-氢原子的反应

苯甲醛二甲缩醛是由苯甲醛和甲醇缩合反应获得。它被用作保护基团。

應用

苯甲醛二甲基缩醛用作构建硒代羰基化合物的有效试剂

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

156.2 °F - closed cup

閃點(°C)

69 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

Lot/Batch Number

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1151. Polar influences in radical reactions. Part IV. The abstraction of benzylic hydrogen atoms from substituted benzyl methyl ethers and benzaldehyde dimethyl acetals by atomic bromine.
Huang RL and Lee KH.
Journal of the Chemical Society, 5963-5969 (1964)
Tetrahedron Letters, 33, 7865-7865 (1992)
N Sakairi et al.
Carbohydrate research, 246, 61-73 (1993-08-17)
Treatment of phenyl alpha-maltoside with an excess of alpha, alpha-dimethoxytoluene in the presence of (+)-10-camphorsulfonic acid, followed by partial hydrolysis to remove unstable acyclic acetal substituents, gave phenyl 3,2':4',6'-di-O-benzylidene-alpha-maltoside. Thus, one of the benzylidene groups formed an eight-membered cyclic acetal
Simona Matrella et al.
Macromolecular bioscience, 15(7), 927-940 (2015-03-18)
Intrinsic antimicrobial thermoplastic A(BC)n copolymers (n = 1, 2, 4), where A was poly(ethylene glycol) (PEG), BC was a random chain of methylmethacrylate (MMA), and alkyl-aminoethyl methacrylate (AAEMA), were synthesized and the antimicrobial activity and hemolyticity were evaluated on plaques obtained by

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