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化驗
98%
形狀
solid
mp
103-105 °C (lit.)
SMILES 字串
[O-][n+]1ccc2ccccc2c1
InChI
1S/C9H7NO/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H
InChI 密鑰
RZIAABRFQASVSW-UHFFFAOYSA-N
一般說明
已经通过稳定光照射和闪光光谱法研究了异喹啉N-氧化物在甲醇或水中的光化学异构化。它是异喹啉衍生物的有用中间体。在空气中的超声辐射下,它会导致富勒烯C60发生氧化。
應用
异喹啉N-氧化物被用于合成 N-烷氧基异喹啉鎓和N-烷氧基4-苯基吡啶鎓离子封端的聚苯乙烯。
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
Ultrasonics, 42(1-9), 611-615 (2004-03-30)
The reaction of C60 with various amine N-oxides such as 3-picoline N-oxide (Aldrich 98.0%), pyridine N-oxide hydrate (Aldrich 95.0%), quinoline N-oxide (Aldrich 97.0%), isoquinoline N-oxide (Aldrich 98.0%) under ultrasonic irradiation in air at 25-43 degrees C causes the oxidation of
N-alkoxy pyridinium ion terminated polystyrenes: A facile route to photoinduced block copolymerization.
Journal of Polymer Science Part A: Polymer Chemistry, 45(3), 423-428 (2007)
The primary photochemical process of isoquinoline N-oxide in hydroxylic solvents.
Bulletin of the Chemical Society of Japan, 46, 3658-3662 (1973)
Iodine-mediated electrophilic cyclization of 2-alkynylbenzaldoximes leading to the formation of iodoisoquinoline N-oxides.
Tetrahedron Letters, 49(38), 5531-5533 (2008)
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method
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