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About This Item
线性分子式:
CH3CH2OCOCH2COCl
CAS号:
分子量:
150.56
Beilstein:
636215
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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等級
technical grade
品質等級
折射率
n20/D 1.429 (lit.)
bp
79-80 °C/25 mmHg (lit.)
密度
1.176 g/mL at 25 °C (lit.)
官能基
acyl chloride
ester
儲存溫度
2-8°C
SMILES 字串
CCOC(=O)CC(Cl)=O
InChI
1S/C5H7ClO3/c1-2-9-5(8)3-4(6)7/h2-3H2,1H3
InChI 密鑰
KWFADUNOPOSMIJ-UHFFFAOYSA-N
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一般說明
丙二酸单乙酯酰氯是炔丙醇、肼和胺的通用酰化剂。
應用
丙二酸单乙酯酰氯用于合成以下下物质：
- 液晶甲基富勒烯树枝状聚合物
- 3,5-二取代的 1,2,4-恶二唑衍生物，可能是拟肽的合成砌块
- 3-吡咯啉-2-酮，通过与炔丙基胺的酰胺化反应和随后的碱催化的 5-exo-dig 环化反应
炔丙醇、肼和胺的通用酰化剂。
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
安全危害
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
147.2 °F - closed cup
閃點（°C）
64 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Sudarat Yenjai et al.
Journal of photochemistry and photobiology. B, Biology, 186, 23-30 (2018-07-11)
Rational design of photoreagents with systematic modifications of their structures can provide valuable information for a better understanding of the protein photocleavage mechanism by these reagents. Variation of the length of the linker connecting the photoactive moiety with the protein
Liquid-crystalline methanofullerodendrimers which display columnar mesomorphism.
Maringa N, et al.
Journal of Materials Chemistry, 18(13), 1524-1534 (2008)
N A Meanwell et al.
Journal of medicinal chemistry, 36(24), 3871-3883 (1993-11-26)
The 4,5-diphenyloxazole derivatives 2-4 were previously identified as nonprostanoid prostacyclin (PGI2) mimetics. A series of derivatives of 2-4 bearing substitutents at the carbon atom alpha to the oxazole ring were synthesized and evaluated as inhibitors of ADP-induced aggregation of human
Synlett, 65-65 (1993)
Synthesis of 3, 5-disubstituted 1, 2, 4-oxadiazoles as peptidomimetic building blocks.
Jakopin Z, et al.
Tetrahedron Letters, 48(8), 1465-1468 (2007)
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