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160938

Sigma-Aldrich

Resolve-Al EuFOD

99%

别名:

Eu(fod)3, Sievers 试剂, 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕(III), 三(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮酸)铕

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About This Item

线性分子式:
Eu(OCC(CH3)3CHCOCF2CF2CF3)3
CAS号:
17631-68-4
分子量:
1037.49
EC號碼:
241-616-1
MDL號碼:
MFCD00064655
分類程式碼代碼:
12161600
PubChem物質ID:
24849895
NACRES:
NA.22

化驗

99%

形狀

solid

反應適用性

core: erbium
reagent type: catalyst

mp

203-207 °C

SMILES 字串

CC(C)(C)C(\O[Eu](O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/3C10H11F7O2.Eu/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;

InChI 密鑰

PTQJQBFRLLGICD-VNGPFPIXSA-K

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相关类别

一般說明

在氧代琥珀酸盐衍生物的自由基介导烯丙基化反应中增强立体选择性。

應用

当与 Resolve-Al AgFOD 结合使用时，可为芳香族化合物、铵盐以及锍和异硫脲卤化物提供有效的 NMR 位移试剂。

法律資訊

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
BGBB6126V
BGBC2984V
03820HJ
01204HJ
08529MH

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The Journal of Organic Chemistry, 50, 1322-1322 (1985)
Journal of the American Chemical Society, 102, 5903-5903 (1980)
K D Schulze et al.
Biochimica et biophysica acta, 1467(1), 27-38 (2000-08-10)
Investigating the action of the fluorinated europium complex Eu(fod)3 on lipid membranes we found that the complex facilitates the ion transfer through the membrane. Electric measurements on planar lipid membranes showed that the membrane conductivity increases considerably by insertion of
A B Ellis et al.
Proceedings of the National Academy of Sciences of the United States of America, 78(7), 3993-3997 (1981-07-01)
Several retinal isomers are shown to form adducts in isooctane solution with a lanthanide beta-diketonate complex, tris(6,6,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III) [Eu(fod)3]. The adducts are characterized by an absorption band whose lambda max at approximately 420 nm is red-shifted by approximately 60 nm from
J P Caldwell et al.
Journal of forensic sciences, 46(6), 1332-1341 (2001-11-21)
The utilization of the lanthanide shift reagent tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato) europium (III) [Eu(fod)3] as a simple one-step reagent for the luminescent visualization of latent fingerprints has been investigated. UV excitation of Eu(fod)3-treated prints, achieved by using a hand-held UV lamp or
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