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Merck

157457

Sigma-Aldrich

3,5-二叔丁基邻苯醌

98%

别名:

3,5-二叔丁基-1,2-苯醌, 3,5-二叔丁基-o-苯醌, 3,5-二叔丁基环己基-3,5-二烯-1,2-二酮, 3,5-二叔丁基苯醌, 3,5-双(1,1-二甲基乙基)-3,5-环己二烯-1,2-二酮, 4,6-二叔丁基-1,2-苯醌, 4,6-二叔丁基-o-苯醌

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About This Item

线性分子式:
[(CH3)3C]2C6H2(=O)2
CAS号:
分子量:
220.31
Beilstein:
2047944
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

solid

mp

112-114 °C (lit.)

SMILES 字串

CC(C)(C)C1=CC(=O)C(=O)C(=C1)C(C)(C)C

InChI

1S/C14H20O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8H,1-6H3

InChI 密鑰

NOUZOVBGCDDMSX-UHFFFAOYSA-N

基因資訊

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一般說明

次膦基桥联络合物[[Fe25-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) 与3,5-二--丁基-o-苯醌的反应已有报道。

應用

3,5-二--丁基-o-苯醌可用于制备苯并恶唑衍生物配体。其可与无环二烯发生杂原子Diels Alder反应,制备1,4-苯二恶英。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chinmoy Das et al.
Dalton transactions (Cambridge, England : 2003), 46(5), 1439-1448 (2017-01-11)
The reaction of anhydrous MCl
Determination of natural thiols by liquid chromatography after derivatization with 3,5-di-tert.-butyl-1,2-benzoquinone.
Y Imai et al.
Journal of chromatography, 420(2), 404-410 (1987-09-25)
Olga Iasco et al.
Inorganic chemistry, 51(4), 2588-2596 (2012-01-12)
Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or 1,3-diamino-2-hydroxypropane in methanol. Condensation of DTBBQ with ethanolamine gives the expected 5,7-di-tert-butyl-2-methylenhydroxylbenzoxazole (HL1) while with 1,3-diamino-2-hydroxypropane it gives (2-hydroxyethyl-2-{2,4-bis(1,1-dimethylethyl)-1-phenol-6 amino}-2{5,7-di-tert-butyl-benzoxazole}) (H(2)L2) with only one benzoxazole
Akira Kotani et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(11), 1473-1476 (2003-12-03)
A disposable voltammetric cell using three pencil leads as working, reference, and counter electrodes was developed for determining the titratable acidity, i.e. the acid content in vinegar. The materials of the pencil leads were graphite-reinforcement carbons (GRCs). A voltammetric determination
Victor A Timoshchuk et al.
Nucleosides, nucleotides & nucleic acids, 28(5), 464-472 (2010-02-26)
A new method for the synthesis of fluorescent nucleosides has been developed. It has been shown that a reaction of benzoquinone with aminopropenyl group at C-5-position of 2'-deoxyuridine or 2'-deoxycytidine and aminopropynyl group at the C-7-position of 8-aza-7-deazaadenosine under extremely

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